15936-45-5

Basic information

• Product Name: N-(3-Methyl-2-butenyl)phthalimide
• Synonyms: N-(3-Methyl-2-butenyl)phthalimide;N-(3-METHYL-2-BUTEN-1-YL)PHTHALIMIDE;2-(3-methylbut-2-enyl)isoindoline-1,3-dione
• CAS NO: 15936-45-5
• Molecular Formula: C13H13NO2
• Molecular Weight: 215.24782
• Mol File: 15936-45-5.mol
• Article Data: 18

Chemical Properties

• Melting Point: 97-99 °C
• Boiling Point: 327.9°Cat760mmHg
• Flash Point: 139°C
• Appearance: /
• Density: 1.175g/cm³
• Vapor Pressure: 0.000196mmHg at 25°C
• Refractive Index: 1.578
• PKA: -2.12±0.20(Predicted)
• CAS DataBase Reference: N-(3-Methyl-2-butenyl)phthalimide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-Methyl-2-butenyl)phthalimide(15936-45-5)
• EPA Substance Registry System: N-(3-Methyl-2-butenyl)phthalimide(15936-45-5)

Safety Data

• Hazardous Substances Data: 15936-45-5(Hazardous Substances Data)

Usage

General Description

N-(3-Methyl-2-butenyl)phthalimide is a chemical compound with the molecular formula C14H13NO2. It is commonly used as a herbicidal intermediate in the production of various herbicides. The compound is an intermediate in the synthesis of the herbicide flumioxazin and is also used as a precursor in the production of other agrochemicals. It is known for its ability to inhibit the growth of unwanted plants and is widely used in agriculture and horticulture. Additionally, the compound has applications in pharmaceutical and chemical industries due to its unique chemical properties.

InChI:InChI=1/C13H13NO2/c1-9(2)7-8-14-12(15)10-5-3-4-6-11(10)13(14)16/h3-7H,8H2,1-2H3

Upstream product

• 1985-88-2 4-chloro-2-methyl-2-butanol 
• 1198105-11-1 2-(3-bromo-3-methylbutyl)-isoindoline-1,3-dione 
• 75-05-8 acetonitrile 
• 1074-82-4 potassium phtalimide 
• 136918-14-4 phthalimide 
• 78-79-5 isoprene 
• 503-60-6 3,3-dimethyl-allyl chloride 
• 870-63-3 prenyl bromide 
• 556-82-1 3-methyl-2-buten-1-ol 
• 56-23-5 tetrachloromethane 
• 624-96-4 1,3-dichloro-3-methylbutane 
• 33081-78-6 sodium phthalimide 
• 41004-19-7 1-iodo-3-methyl-but-2-ene 

Downstream Products

• 13822-06-5 3,3-dimethylallylamine 
• 1174427-20-3 (+/-)-3-tert-butyloxycarbonylaminomethyl-4,4-dimethyl azetidin-2-one 
• 1449106-57-3 C₁₈H₂₁NOSe 
• 1449106-58-4 N-cyano-N-(3-methyl-3-(phenylselanyl)butyl)benzamide 
• 1198105-13-3 3-methyl-3-phenylselanyl-butylamine 
• 26728-58-5 (3-methyl-2-butenyl)amine hydrochloride 

Relevant articles and documents

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Amination of Carbenium Ions Generated by Directed Protonolysis of Cyclopropane

Directed intramolecular protonolyis of the cyclopropane C-C bond is demonstrated as a strategy to generate carbenium ions. This intermediate can be subjected to amination with nitriles under Ritter reaction conditions. Directing groups such as carbamate, carboxamide, urea, ester, and ketone were found to be efficient for regioselective anti-Markovnikov cleavage of cyclopropane. Depending on the directing group, the amination provided orthogonally protected 1,4-diamine, ?-amino carboxylic, and ?-amino ketone derivatives.

Poly-β-peptides from functionalized β-lactam monomers and antibacterial compositions containing same

Disclosed is a method of making β-polypeptides. The method includes polymerizing β-lactam-containing monomers in the presence of a base initiator and a co-initiator which is not a metal-containing molecule to yield the product β-polypeptides. Specifically disclosed are methods wherein the base initiator is potassium t-butoxide, lithium bis(trimethylsilyl)amide (LiN(TMS)2), potassium bis(trimethyl-silyl)amide, and sodium ethoxide, and the reaction is carried out in a solvent such as chloroform, dichloromethane, dimethylsulfoxide, or tetrahydrofuran.