16251-78-8Relevant articles and documents
Palladium(II)-catalyzed hydroarylation of α,β-unsaturated aldehydes and ketones with triarylstibines in the presence of silver acetate
Cho, Chan Sik,Tanabe, Koichiro,Uemura, Sakae
, p. 1275 - 1278 (1994)
Triarylstibines react with α,β-unsaturated aldehydes and ketones in acetic acid at 25°C in the presence of silver acetate and a catalytic amount of palladium(II) acetate to afford the hydroarylation products by conjugate addition in good yields.
Copper(I)-catalyzed stereodivergent propargylation of N-acetyl mannosamine for protecting group minimal synthesis of C3-substituted sialic acids
Ishizawa, Kouhei,Majima, Sohei,Wei, Xiao-Feng,Mitsunuma, Harunobu,Shimizu, Yohei,Kanai, Motomu
, p. 10615 - 10628 (2019/09/30)
Copper(I)-catalyzed stereodivergent nucleophilic propargylation at the anomeric carbon of unprotected N-acetyl mannosamine was developed using 3-substituted allenylboronates as a nucleophile. The homopropargylic alcohol products contained two contiguous s
Stereospecific Pd(0)-Catalyzed Arylation of an Allylic Hydroxy Phosphonate Derivative: Formal Synthesis of (S)-(+)-ar-Turmerone
Rowe, Bradley J.,Spilling, Christopher D.
, p. 9502 - 9505 (2007/10/03)
Reaction of the (1S)-allylic hydroxy phosphonate 1(S) with methyl chloroformate in pyridine yields the corresponding carbonate 3(S). The carbonate 3(S) undergoes a palladium-catalyzed arylation with p-tolyl tributylstannane to give both the 1E and 1Z viny
