16596-02-4

Basic information

• Product Name: Methanimidamide, N,N'-bis(3-methylphenyl)-
• CAS NO: 16596-02-4
• Molecular Formula: C15H16N2
• Molecular Weight: 224.305
• Mol File: 16596-02-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Methanimidamide, N,N'-bis(3-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanimidamide, N,N'-bis(3-methylphenyl)-(16596-02-4)
• EPA Substance Registry System: Methanimidamide, N,N'-bis(3-methylphenyl)-(16596-02-4)

Safety Data

• Hazardous Substances Data: 16596-02-4(Hazardous Substances Data)

Upstream product

• 3085-53-8 N-formyl-m-toluidine 
• 122-51-0 orthoformic acid triethyl ester 
• 108-44-1 1-amino-3-methylbenzene 
• 64-19-7 acetic acid 
• 620-50-8 N,N'-di(m-tolyl)urea 
• 621-40-9 (3-methylphenyl)thiourea 
• 68-12-2 N,N-dimethyl-formamide 
• 620-51-9 N,N'-di(3-methylphenyl)thiourea 
• 75-44-5 phosgene 
• 141-53-7 sodium formate 
• 638-03-9 m-toluidine hydrochloride 
• 64-18-6 formic acid 

Downstream Products

• 27770-00-9 tris-(4-amino-2-methyl-phenyl)-methane 
• 7030-60-6 N,N'-di-m-tolyl-ethylenediamine 
• 94803-38-0 1.3-Diamino-N_.N'-di-m-tolyl-propan 
• 111066-85-4 4-isobutyl-3,5-dimethyl-2-[2-(3-methyl-anilino)-vinyl]-oxazolium; iodide 
• 99117-41-6 4-isobutyl-3,5-dimethyl-2-[2-(3-methyl-anilino)-vinyl]-thiazolium; iodide 
• 94064-25-2 3-(3-methylphenyl)-4(3H)-quinazolinone 
• 130685-71-1 4-Cyan-3-(3-methyl-phenylamino)-benzo<4,5>thieno<2,3-c>pyridin-9,9-dioxid 
• 49754-72-5 1,1-Dimethyl-3-m-tolyl-3-[(E)-m-tolylimino-methyl]-urea 

Relevant articles and documents

ORGANOMETALLIC COMPOUND, LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND ELECTRONIC APPARATUS INCLUDING THE LIGHT-EMITTING DEVICE

An organometallic compound represented by Formula 1 is provided: [in-line-formulae]M(L1)n1(L2)n2??[Formula 1][/in-line-formulae] [in-line-formulae]*-(T4)a4-(R4)b4??[Formula 2A][/in-line-formulae] L1 in Formula 1 is a ligand represented by Formula 2, Z4 in Formula 2 is represented by Formula 2A, and a complete description of Formulae 1, 2, and 2A is described in the specification. A light-emitting device including the organometallic compound and an electronic apparatus including the light-emitting device are also provided.

Catalyst-Free Synthesis of Aryl Diamines via a Three-Step Reaction Process

The formation of C-N bonds with aryl amines is one of the most widely studied reactions in organic chemistry. Despite this, it is still highly challenging, often requiring expensive, precious metal-based catalysts. Here we report an easy catalyst-free methodology for constructing C-N bonds. The method, which proceeds via the in situ formation of closed ring amidinium ions, allows the preparation of a series of symmetrical and/or unsymmetrical aryl diamines in notably high yields (82-98%) and purity and with a variety of different substituents. The methodology is shown successful for the preparation of aryl diamines having para- and/or meta-substituted carboxyl, nitro, bromo, methoxy, or methyl groups. This green synthetic pathway, which is catalyst free, requires only three steps, and proceeds without the need for purification. Further, it is a new sustainable, economically viable method to achieve an otherwise challenging bond formation.

Pushing back the limits of hydrosilylation: Unprecedented catalytic reduction of organic ureas to formamidines

Pushing back the limits: A novel catalytic transformation has been designed to prepare formamidine derivatives by reduction of substituted ureas with hydrosilanes. Simple iron catalysts based on commercially available iron salts and phosphine ligands prov