17988-58-8

Basic information

• Product Name: 12-<(phenylthio)ethyl>trimethylsilane
• Synonyms: 12-<(phenylthio)ethyl>trimethylsilane
• CAS NO: 17988-58-8
• Molecular Weight: 210.415
• Mol File: 17988-58-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 12-<(phenylthio)ethyl>trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: 12-<(phenylthio)ethyl>trimethylsilane(17988-58-8)
• EPA Substance Registry System: 12-<(phenylthio)ethyl>trimethylsilane(17988-58-8)

Safety Data

• Hazardous Substances Data: 17988-58-8(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 622-38-8 Ethyl phenyl sulfide 
• 13307-56-7 1,1-bis(phenylthio)ethane 
• 3561-67-9 bis(phenylthio)methane 
• 13307-75-0 (phenylthio)methyllithium 
• 108-98-5 thiophenol 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 100-68-5 methyl-phenyl-thioether 
• 74-88-4 methyl iodide 
• 30536-77-7 <(phenylthio)(trimethylsilyl)methyl>lithium 
• 7787-87-3 (1-chloroethyl)trimethylsilane 

Downstream Products

• 107014-77-7 2-phenylthiohept-2-ene 
• 1003-64-1 ethylidenecyclohexane 
• 767-99-7 2-phenylbut-2-ene 
• 91787-40-5 2-phenylsulphonyl-2-trimethylsilylhexane 
• 91787-44-9 2-phenylthio-2-trimethylsilylhexane 
• 513-35-9 2-methyl-but-2-ene 
• 592-43-8 2-hexene 
• 109-68-2 2-pentene 
• 637-50-3 1-phenylpropene 
• 91787-35-8 1-phenylsulphonyl-1-trimethylsilylethane 
• 40110-36-9 1-Trimethylsilyl-1-phenylsulfinylethan 
• 62762-20-3 1-phenylthio-1-trimethylsilylethene 

Relevant articles and documents

Metallation Reactions. XVIII. Regioselective metallation of (alkylthio)benzenes by superbases

(Alkylthio)benzenes were monometallated at the alpha position by a stoichiometric mixture of butyllithium and potassium t-butoxide and bimetallated at both the alpha and the ortho positions by two equivalents of the same reagent.

A NEW METHOD FOR PREPARING 1-PHENYLTHIO-1-TRIMETHYLSILYLALKANES: THE PREPARATION OF α-SILYLCARBANIONS AND OLEFINS.

1-Phenylthio-1-trimethylsilylalkanes(1) are prepared in high yield from 1,1-bis(phenylthio)acetals(2) by reaction with lithium naphthalenide(3) followed by chlorotrimethylsilane. α-Silylcarbanions are formed from the alkanes(1) and lithium naphthalenide(3).Subsequent reaction with carbonyl compounds gave the olefins(4) via the Peterson reaction.