30536-77-7

Basic information

• Product Name: Lithium, [(phenylthio)(trimethylsilyl)methyl]-
• CAS NO: 30536-77-7
• Molecular Formula: C10H15LiSSi
• Molecular Weight: 202.322
• Mol File: 30536-77-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Lithium, [(phenylthio)(trimethylsilyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, [(phenylthio)(trimethylsilyl)methyl]-(30536-77-7)
• EPA Substance Registry System: Lithium, [(phenylthio)(trimethylsilyl)methyl]-(30536-77-7)

Safety Data

• Hazardous Substances Data: 30536-77-7(Hazardous Substances Data)

Upstream product

• 13307-75-0 (phenylthio)methyllithium 
• 100-68-5 methyl-phenyl-thioether 
• 3561-67-9 bis(phenylthio)methane 

Downstream Products

• 79409-22-6 Trimethyl-[1-phenylsulfanyl-4-(tetrahydro-pyran-2-yloxy)-butyl]-silane 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 64732-73-6 trimethyl(2-methyl-1-(phenylthio)propyl)silane 
• 76200-37-8 trimethyl(1-(phenylthio)pentyl)silane 
• 74032-25-0 1-((Z)-1-Phenyl-2-phenylsulfanyl-vinyl)-aziridine 
• 74032-24-9 1-((E)-1-Phenyl-2-phenylsulfanyl-vinyl)-aziridine 
• 75349-67-6 1-[2-(tert-Butyl-dimethyl-silanyloxy)-4-phenylsulfanyl-4-trimethylsilanyl-butyl]-4-methoxy-benzene 
• 74032-20-5 {2,2-Dimethyl-1-[1-phenylsulfanyl-meth-(E)-ylidene]-propyl}-dimethyl-amine 
• 74032-21-6 {2,2-Dimethyl-1-[1-phenylsulfanyl-meth-(Z)-ylidene]-propyl}-dimethyl-amine 
• 1822-73-7 phenylthioethylene 
• 62761-90-4 α,α-bis(trimethylsilyl)methylphenyl sulfide 
• 71341-87-2 3-<(phenylthio)methylene>-1-cyclohexene 
• 79409-24-8 3-<(phenylthio)(trimethylsilyl)methyl>cyclohexanone 
• 74032-26-1 (E)-β-phenylthio-α-piperidinostyrene 

Relevant articles and documents

Synthesis of Aldehydes from Phenylthiotrimethylsilylmethane

Phenylthiotrimethylsilylmethyl-lithium (4) reacts with alkyl halides to give 1-phenylthio-1-trimethylsilylalkanes (5), which can also be prepared by the addition of alkyl-lithium to 1-phenylthio-1-trimethylsilylethene (8), or from bis(phenylthio)acetals (11).The 1-phenylthio-1-trimethylsilylalkanes (5) can be converted into the corresponding aldehyde (15) by oxidation to the sulphoxide (13), thermal rearrangement, and hydrolysis of the resultant O-silyl thioacetal (14).