64732-73-6

Basic information

• Product Name: Silane, trimethyl[2-methyl-1-(phenylthio)propyl]-
• CAS NO: 64732-73-6
• Molecular Formula: C13H22SSi
• Molecular Weight: 238.469
• Mol File: 64732-73-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[2-methyl-1-(phenylthio)propyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[2-methyl-1-(phenylthio)propyl]-(64732-73-6)
• EPA Substance Registry System: Silane, trimethyl[2-methyl-1-(phenylthio)propyl]-(64732-73-6)

Safety Data

• Hazardous Substances Data: 64732-73-6(Hazardous Substances Data)

Upstream product

• 75-30-9 2-iodo-propane 
• 108-98-5 thiophenol 
• 13307-75-0 (phenylthio)methyllithium 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 100-68-5 methyl-phenyl-thioether 
• 3561-67-9 bis(phenylthio)methane 
• 75-77-4 chloro-trimethyl-silane 
• 54905-13-4 isopropyl aldehyde dithiophenylacetal 
• 30536-77-7 <(phenylthio)(trimethylsilyl)methyl>lithium 

Downstream Products

• 87505-45-1 (1-Benzenesulfinyl-2-methyl-propyl)-trimethyl-silane 

Relevant articles and documents

Strategic Trimethylsilyldiazomethane Insertion into pinB-SR Followed by Selective Alkylations

The insertion of the diazo derivative Me3SiCHN2 into pinB-SR σ bonds (R = Ph, Tol, Bn) allows a direct synthesis of multisubstituted H-C(SR)(Bpin)(SiMe3) compounds. Consecutive base-assisted transformations of HC(S)(B) (Si

A NEW METHOD FOR PREPARING 1-PHENYLTHIO-1-TRIMETHYLSILYLALKANES: THE PREPARATION OF α-SILYLCARBANIONS AND OLEFINS.

1-Phenylthio-1-trimethylsilylalkanes(1) are prepared in high yield from 1,1-bis(phenylthio)acetals(2) by reaction with lithium naphthalenide(3) followed by chlorotrimethylsilane. α-Silylcarbanions are formed from the alkanes(1) and lithium naphthalenide(3).Subsequent reaction with carbonyl compounds gave the olefins(4) via the Peterson reaction.