19347-08-1

Basic information

• Product Name: 1-Propanone, 2-(acetyloxy)-1-phenyl-
• CAS NO: 19347-08-1
• Molecular Formula: C11H12O3
• Molecular Weight: 192.214
• Mol File: 19347-08-1.mol
• Article Data: 35

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-(acetyloxy)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-(acetyloxy)-1-phenyl-(19347-08-1)
• EPA Substance Registry System: 1-Propanone, 2-(acetyloxy)-1-phenyl-(19347-08-1)

Safety Data

• Hazardous Substances Data: 19347-08-1(Hazardous Substances Data)

Upstream product

• 127-08-2 potassium acetate 
• 2114-00-3 2-bromo-1-phenyl-1-propanone 
• 127-09-3 sodium acetate 
• 2570-63-0 thallium(III) triacetate 
• 93-55-0 1-phenyl-propan-1-one 
• 5650-40-8 2-hydroxypropiophenone 
• 75-36-5 acetyl chloride 
• 98990-64-8 4-Nitro-benzenesulfonic acid 1-methyl-2-oxo-2-phenyl-ethyl ester 
• 64-19-7 acetic acid 
• 127-19-5 N,N-dimethyl acetamide 
• 638-38-0 manganese triacetate 
• 838-85-7 diphenyl hydrogen phosphate 
• 315186-60-8 N-tosyl-4-[(diacetoxy)iodo]pyrazole 
• 38939-83-2 2-acetoxypropionyl chloride 

Downstream Products

• 107002-89-1 (E)-(2-acetoxy-1-phenylpropylidene)(benzyloxy)amine 
• 107002-90-4 (Z)-(2-acetoxy-1-phenylpropylidene)(benzyloxy)amine 
• 5650-40-8 (R)-2-hydroxy-1-phenylpropan-1-one 
• 91111-01-2 (R)-1-oxo-1-phenylpropan-2-yl acetate 
• 79314-55-9 3-hydroxy-2-methyl-1-phenylpentan-1-one 
• 5650-40-8 (S)-2-hydroxypropiophenone 
• 93-55-0 1-phenyl-propan-1-one 
• 40421-52-1 (1RS,2SR)-1-phenylpropane-1,2-diol 
• 116701-68-9 erythro-1-<(benzyloxy)amino>-1-phenyl-2-propyl acetate 
• 116701-69-0 threo-1-<(benzyloxy)amino>-1-phenyl-2-propyl acetate 
• 116701-70-3 erythro-1-<(benzyloxy)amino>-1-phenyl-2-propanol 
• 24257-70-3 (+/-)-1-hydroxy-1-phenyl-2-propyl acetate 
• 88928-40-9 2,3,5-trimethyl-4-phenyl-furan 
• 1855-09-0 1-phenyl-1,2-propandiol 

Relevant articles and documents

NMR determination of absolute configuration of α-acyloxy ketones

Determination of the absolute configuration of several acyclic α-acyloxy-ketones, and δ-ketobutanolides, in the presence of a chiral solvating agent, by low temperature and low concentration 1H NMR analysis, is reported.

Sulfur-mediated difunctionalization of internal and terminal alkynes for the synthesis of α-acetoxy ketones

The sulfur-mediated difunctionalization of alkynes is reported to give α-acetoxy ketones in a one-pot operation under mild conditions with 19–92% yield. By using wet potassium acetate as both the aqueous base and nucleophilic reagent, both terminal alkynes and internal alkynes could be converted into the α-acetoxy ketone products.

Continuous-Flow Electrochemical Generator of Hypervalent Iodine Reagents: Synthetic Applications

An efficient and reliable electrochemical generator of hypervalent iodine reagents has been developed. In the anodic oxidation of iodoarenes to hypervalent iodine reagents under flow conditions, the use of electricity replaces hazardous and costly chemical oxidants. Unstable hypervalent iodine reagents can be prepared easily and coupled with different substrates to achieve oxidative transformations in high yields. The unstable, electrochemically generated reagents can also easily be transformed into classic bench-stable hypervalent iodine reagents through ligand exchange. The combination of electrochemical and flow-chemistry advantages largely improves the ecological footprint of the overall process compared to conventional approaches.