20215-55-8Relevant articles and documents
Cu-catalyzed intermolecular oxyalkylation of styrenes under air: Access to diverse iminolactones
Lv, Yunhe,Pu, Weiya,Mao, Shukuan,Ren, Xiaoran,Wu, Yingtao,Cui, Hao
, p. 41723 - 41726 (2017)
A practical, simple, and efficient copper-catalyzed highly regioselective oxyalkylation of styrenes and readily available α-bromoacetamides under air is realized. This reaction exhibits a wide range of functional group tolerance in styrenes and α-bromoacetamides to afford iminolactones.
Erratum: Cu-Catalyzed Three-Component Carboamination of Alkenes (J. Am. Chem. Soc. (2018) 140:1 (58?61) DOI: 10.1021/jacs.7b10529)
Gockel, Samuel N.,Buchanan, Travis L.,Hull, Kami L.
supporting information, p. 6019 - 6020 (2021/05/13)
Pages 59 and 60. We have identified an error in the structural analysis of compounds presented in our publication detailing. (Table presented).
Catalytic Redox Chain Ring Opening of Lactones with Quinones to Synthesize Quinone-Containing Carboxylic Acids
Xu, Xiao-Long,Li, Zhi
supporting information, p. 5078 - 5081 (2019/09/03)
Catalytic ring opening of five- to eight-membered lactones with quinones is achieved through a redox chain mechanism. With low loading of a simple metal triflate Lewis acid catalyst and a chain initiator, C-H bonds of many quinones were efficiently functionalized with carboxylic acid-containing side chains. This method also features 100% atom economy and wide substrate scope. A novel route to the anti-asthma drug Seratrodast was developed. Mechanism study suggests that the redox chain reaction likely undergoes a carbocation intermediate.
Cu-Catalyzed Three-Component Carboamination of Alkenes
Gockel, Samuel N.,Buchanan, Travis L.,Hull, Kami L.
supporting information, p. 58 - 61 (2018/01/17)
Copper-catalyzed intermolecular carboamination of alkenes with α-halocarbonyls and amines is presented with 42 examples. Electron rich, electron poor, and internal styrenes, as well as α-olefins, are functionalized with α-halocarbonyls and aryl or aliphat
