2046-39-1Relevant articles and documents
Direct conversion of aldehydes to acyl azides using tert-butyl hypochlorite
Arote, Nitin D.,Akamanchi, Krishnacharya G.
, p. 5661 - 5664 (2007)
A general method, for the direct conversion of aldehydes to acyl azides using tert-butyl hypochlorite and sodium azide is described. The method is simple and occurs under mild conditions.
Boron-Containing Nucleosides. 1. Synthesis of the Novel Heterocycle 2-Benzyl-1,4-dihydro-1-hydroxythieno[3,2-c7] [1,5,2]diazaborin-3(2H)-one: A Thieno-fused 4-Borauracil
Graham, Steven M.,Ohrtman, Loralee M.
, p. 887 - 890 (1998)
The synthesis of the novel boron-containing nucleobase 2-benzy]-1,4-dihydro-l-hydroxythieno[3,2-c]-[1,5,2]diazaborin-3(2H)-one (8), a thieno-fused 4-borauracil, is described. Compound 8 was prepared in three steps starting from 2-thiophenecarbonyl chlorid
An Improved Synthesis of Polyfunctional Acyl Azides in PEG 400
Widyan, Khalid
, p. 120 - 126 (2021/03/16)
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Synthesis of Acyl Phosphoramidates Employing a Modified Staudinger Reaction
Currie, Iain,Sleebs, Brad E.
supporting information, p. 464 - 468 (2021/02/03)
A one-step synthesis of acyl phosphoramidates from a variety of functionalized acyl azides has been developed employing trimethylsilyl chloride as an activating agent in a modified Staudinger reaction. The methodology was further adapted to include the in situ generation of the acyl azides from a diverse selection of carboxylic acids and hydrazide starting synthons. The reaction scope was extended to include the synthesis of imidodiphosphates and the natural product Microcin C.
Palladium-Catalyzed One-Pot Synthesis of N -Sulfonyl, N -Phosphoryl, and N -Acyl Guanidines
Qiao, Guanyu,Zhang, Zhen,Huang, Baoliang,Zhu, Liu,Xiao, Fan,Zhang, Zhenhua
supporting information, p. 330 - 340 (2018/01/12)
An efficient palladium-catalyzed cascade reaction of azides with isonitrile and amines is presented; it offers an alternative facile approach toward N -sulfonyl-, N -phosphoryl-, and N -acyl-functionalized guanidines in excellent yield. These series of substituted guanidines exhibit potential biological and pharmacological activities. In addition, the less reactive intermediate benzoyl carbodiimide could be isolated by silica gel column flash chromatography in moderate yield.