22391-06-6

Basic information

• Product Name: 4-nitrophenyl-1,3-oxathiolane
• Synonyms: 4-nitrophenyl-1,3-oxathiolane
• CAS NO: 22391-06-6
• Molecular Formula: C₉H₉NO₃S
• Molecular Weight: 211.24
• Mol File: 22391-06-6.mol
• Article Data: 29

Chemical Properties

• Melting Point: 78 °C
• Boiling Point: 386.8°Cat760mmHg
• Flash Point: 187.7°C
• Appearance: /
• Density: 1.36g/cm³
• Vapor Pressure: 7.7E-06mmHg at 25°C
• Refractive Index: 1.62
• CAS DataBase Reference: 4-nitrophenyl-1,3-oxathiolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4-nitrophenyl-1,3-oxathiolane(22391-06-6)
• EPA Substance Registry System: 4-nitrophenyl-1,3-oxathiolane(22391-06-6)

Safety Data

• Hazardous Substances Data: 22391-06-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H9NO3S/c11-10(12)8-3-1-7(2-4-8)9-13-5-6-14-9/h1-4,9H,5-6H2

Upstream product

• 2403-62-5 p-nitrobenzaldehyde diethyl acetal 
• 60-24-2 2-hydroxyethanethiol 
• 555-16-8 4-nitrobenzaldehdye 
• 33735-40-9 2,2-diphenyl-1,3-oxathiolane 

Downstream Products

• 2403-53-4 2-(4-nitrophenyl)-1,3-dioxolane 
• 833-64-7 2-(p-nitrophenyl)-1,3-dioxane 
• 41159-02-8 2-(4-nitrophenyl)-1,3-dithiolane 
• 555-16-8 4-nitrobenzaldehdye 
• 62-23-7 4-nitro-benzoic acid 

Relevant articles and documents

Visible light photoredox catalyzed deprotection of 1,3-oxathiolanes

An efficient visible light photoredox catalyzed aerobic deprotection of 1,3-oxathiolanes using organic dye Eosin Y as a photocatalyst is disclosed. The deprotection procedure features the use of a metal-free catalyst, mild conditions, a broad range of substrate scope, and good functional group tolerance. 35 examples were tested under the standard conditions and most of them afforded the deprotected products in modest to high yields.

Nickel(II) chloride hexahydrate catalyzed reaction of aromatic aldehydes with 2-mercaptoethanol: Formation of supramolecular helical assemblage of the product

Various aromatic aldehydes on reaction with 2-mercaptoethanol provided an unanticipated product, bis(2-hydroxyethyl)dithioacetals (3) as the major product along with the expected product 1,3-oxathiolanes (4) in the presence of 0.05 equiv amount of nickel(

An efficient method for the oxathioacetalization of carbonyl compounds using N-bromosaccharin as a catalyst

A mild and highly chemoselective method for the preparation of oxathiolane from aliphatic and aromatic aldehydes and ketones with 2-mercaptoethanol in the presence of catalytic amount of N-bromosaccharin at room temperature is reported.