23450-12-6

Basic information

• Product Name: 4-Benzyl-benzoesaeurephenylester
• Synonyms: 4-Benzyl-benzoesaeurephenylester
• CAS NO: 23450-12-6
• Molecular Weight: 288.346
• Mol File: 23450-12-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Benzyl-benzoesaeurephenylester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Benzyl-benzoesaeurephenylester(23450-12-6)
• EPA Substance Registry System: 4-Benzyl-benzoesaeurephenylester(23450-12-6)

Safety Data

• Hazardous Substances Data: 23450-12-6(Hazardous Substances Data)

Upstream product

• 620-86-0 4-Benzylbenzoic acid 
• 108-95-2 phenol 
• 100-53-8 phenylmethanethiol 
• 943868-13-1 4-benzylsulfanyl-2,3,5,6-tetrafluoropyridine 
• 5798-76-5 phenyl 4-bromobenzoate 
• 611-95-0 4-carboxybenzophenone 

Downstream Products

• 973-74-0 p-Phenoxycarbonyl-benzhydrylchlorid 
• 973-72-8 p-(carbophenoxy)benzhydryl bromide 

Relevant articles and documents

Desulfurative Ni-Catalyzed Reductive Cross-Coupling of Benzyl Mercaptans/Mercaptoacetates with Aryl Halides

The C-S activation and sulfur removal from native thiols is challenging, which limits their application as feedstock materials in organic synthesis despite their natural abundance. Herein, we introduce a per-/polyfluoroaryl moiety, which serves as a redox-active scaffold, into sp3-hybridized thiols to activate the C-S bond. Using a Ni catalyst with MgBr2 as an additive, the S group can be removed to yield an aliphatic radical that can react with an aryl halide in a reductive cross-coupling.