2403-50-1

Basic information

• Product Name: p-Anisaldehyde ethylene acetal
• Synonyms: 2-(p-Methoxyphenyl)-1,3-dioxolane;4-Methoxybenzaldehyde ethylene acetal;p-Anisaldehyde (ethane-1,2-diyl)acetal;p-Anisaldehyde ethylene acetal
• CAS NO: 2403-50-1
• Molecular Formula: C₁₀H₁₂O₃
• Molecular Weight: 180.2
• Mol File: 2403-50-1.mol
• Article Data: 45

Chemical Properties

• Boiling Point: 281.1°C at 760 mmHg
• Flash Point: 93.1°C
• Appearance: /
• Density: 1.133g/cm³
• Vapor Pressure: 0.00619mmHg at 25°C
• Refractive Index: 1.517
• CAS DataBase Reference: p-Anisaldehyde ethylene acetal(CAS DataBase Reference)
• NIST Chemistry Reference: p-Anisaldehyde ethylene acetal(2403-50-1)
• EPA Substance Registry System: p-Anisaldehyde ethylene acetal(2403-50-1)

Safety Data

• Hazardous Substances Data: 2403-50-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H12O3/c1-11-9-4-2-8(3-5-9)10-12-6-7-13-10/h2-5,10H,6-7H2,1H3

Upstream product

• 7381-30-8 2,2,7,7-tetramethyl-3,6-dioxa-2,7-disilaoctane 
• 123-11-5 4-methoxy-benzaldehyde 
• 13807-89-1 2-(4-methoxybenzyloxy)ethanol 
• 122-51-0 orthoformic acid triethyl ester 
• 107-21-1 ethylene glycol 
• 105-13-5 4-Methoxybenzyl alcohol 
• 646-06-0 1,3-DIOXOLANE 
• 623-12-1 4-chloromethoxybenzene 
• 74733-99-6 2-<2-(2-methoxyethoxy)ethoxy>-1,3-dioxolan 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 13807-89-1 2-(4-methoxybenzyloxy)ethanol 
• 19263-28-6 2-bromoethyl 4-methoxybenzoate 
• 123-11-5 4-methoxy-benzaldehyde 
• 6712-20-5 2-(4-methoxyphenyl)-[1,3]dithiolane 
• 22391-03-3 2-(4-methoxyphenyl)-1,3-oxathiolane 
• 121-98-2 methyl 4-methoxybenzoate 
• 104-87-0 4-methyl-benzaldehyde 
• 637-69-4 4-Methoxystyrene 
• 57479-35-3 8-(4-methoxyphenyl)quinoline 
• 2017-87-0 ethyl (2E)-2-cyano-3-(4-methoxyphenyl)acrylate 
• 105-13-5 4-Methoxybenzyl alcohol 
• 3526-43-0 N-(4-methoxybenzyl)aniline 
• 1450806-16-2 2-(2,2,2-trifluoro-1-(4-methoxyphenyl)ethyl)-1,3-dioxolane 
• 24588-72-5 2-(4-methoxyphenyl)-1,3-dithiane 

Relevant articles and documents

Formation of dioxolane on the surface of silica-sulphuric acid in dry media - Chemoselective protection of aryl aldehydes

Chemoselective protection of aryl aldehydes can be accomplished through the formation of dioxolane on the surface of silica-sulphuric acid under solvent-free conditions where aliphatic aldehydes, dialkyl ketones, aryl alkyl ketones, and diaryl ketones rem

Structure and surface properties of Ni-Al hydrotalcite-like compounds and their catalytic application in highly selective acetalization at room temperature

Ni-Al hydrotalcite-like compounds (Ni-Al HTLCs) containing nitrate anions were synthesized and applied in the acetalization ofp-anisaldehyde with ethylene glycol under mild reaction conditions. The Ni-Al HTLCs showed good selectivity for acetalization and

Inhibition by Water during Heterogeneous Br?nsted Acid Catalysis by Three-Dimensional Crystalline Organic Salts

A new self-assembled and self-healing class of metal free, recyclable, heterogeneous Br?nsted acid catalysts has been developed by the protonation of aniline derivatives (tetrakis(4-aminophenyl)methane, leuco-crystal violet, benzidine, and p-phenylenediamine) with aromatic sulfonic acids (tetrakis(phenyl-4-sulfonic acid)methane, and 2,6-naphthalenedisulfonic acid). As a result, five three-dimensional crystalline organic salts (F-1a, F-1b, F-1c, F-2, and F-3) were obtained, linked by hydrogen bonds and additionally stabilized by the opposite charges of the components. Frameworks F-2 and F-3 were prepared for the first time and characterized by elemental analysis, X-ray structural analysis (for F-2), thermogravimetry, SEM, and FTIR spectroscopy. The catalytic activities of crystalline organic salts F-1-3 have been explored in industrially important epoxide ring-opening and acetal formation reactions. The presence of encapsulated water inside frameworks F-1a and F-2 had an inhibitory effect on the performance of the catalysts. X-ray diffraction analysis of hydrated and dehydrated samples of F-1a and F-2 indicated that water of crystallization served as a cross-linking agent, diminishing the substrate induced "breathing"affinities of the frameworks.

Alcohol Etherification via Alkoxy Radicals Generated by Visible-Light Photoredox Catalysis

A mechanistically divergent method is described that, employing a commercially available hypervalent iodine(III) reagent, generates alkoxy radicals from 1°, 2°, and 3° alcohols and allows their use in the functionalization of C(sp3)-H and C(sp2)-H bonds. This visible-light photoredox catalysis produces alkyl ethers via 1,5/6-hydrogen atom transfer or aryl ethers via 1,5-addition. This mild methodology provides a practical strategy for the synthesis of acetals, orthoesters, tetrahydrofurans, and chromanes.