25438-37-3Relevant articles and documents
Syntheses, structures, molecular and cationic recognitions and catalytic properties of two lanthanide coordination polymers based on a flexible tricarboxylate
Zhu, Yu,Wang, Yan-Mei,Xu, Ji,Liu, Pan,Weththasinha,Wu, Yun-Long,Lu, Xiao-Qing,Xie, Ji-Min
, p. 259 - 264 (2014)
Two lanthanide coordination polymers, namely, {[La(TTTA)(H 2O)2]·2H2O}n (La-TTTA) and [Nd(TTTA)(H2O)2]·2H2O}n (Nd-TTTA) have been hydrothermally synthesized through th
Bifunctional 2D Cd(II)-Based Metal-Organic Framework as Efficient Heterogeneous Catalyst for the Formation of C-C Bond
Hu, Lei,Hao, Gui-Xia,Luo, Hai-Dong,Ke, Chun-Xian,Shi, Guang,Lin, Jia,Lin, Xiao-Ming,Qazi, Umair Yaqub,Cai, Yue-Peng
, p. 2883 - 2889 (2018)
A porous two-dimensional (2D) metal-organic framework (MOF), namely, [Cd(PBA)(DMF)]·DMF (Cd-PBA), has been solvothermally synthesized by the reaction of 5-(4-pyridin-3-yl-benzoylamino)-isophthalic acid ligand (H2PBA) and Cd(II) ions. Structural
Hollow silica nanosphere having functionalized interior surface with thin manganese oxide layer: Nanoreactor framework for size-selective Lewis acid catalysis
Anisur, Rahman Md,Shin, Jongmin,Choi, Hyung Ho,Yeo, Kyung Min,Kang, Eun Joo,Lee, In Su
, p. 10615 - 10621 (2010)
A novel selective nanoscale etching process that generated a well defined hollow nanostructure was developed by treating manganese oxide nanoparticles with a hydroxylamine solution. This selective etching process was used for exploiting a novel method of differentially functionalizing the internal surface of a hollow silica shell with a catalytically active Mn3O 4 layer and creating a novel nanoreactor framework. The nanoreactor fabricated by the newly developed method catalyzed the cyanosilylation reactions of various aromatic aldehydes with size and shape selectivity. Moreover, the substrate selectivity in the cyanosilylation reactions was efficiently tuned by modifying the outer silica shell with silane coupling reagents.
Syntheses, structures and catalytic properties of organic-inorganic hybrid materials constructed from Evans-Showell-type polyoxometalates and zinc-organic coordination units
Fei, Fei,An, Haiyan,Xu, Tieqi,Meng, Changgong
, p. 92092 - 92103 (2016)
Four new organic-inorganic hybrid compounds based on the polyoxoanion [Co2Mo10H4O38]6-, namely [Zn2(H2O)5(4,4′-bipy)3]H2[Co2Mo10
Improving the porosity and catalytic capacity of a zinc paddlewheel metal-organic framework (MOF) through metal-ion metathesis in a single-crystal-to-single-crystal fashion
Yang, Jie,Wang, Xiaoqing,Dai, Fangna,Zhang, Liangliang,Wang, Rongming,Sun, Daofeng
, p. 10649 - 10653 (2014)
Zinc paddlewheel metal-organic frameworks (MOFs) frequently exhibit low stability or complete collapse upon the removal of axial ligands. Hence, there are very few reports on gas adsorption of zinc paddlewheel MOFs. In this work, the N2 and Hs
Lanthanide-Based Metal-Organic Frameworks Containing "v-Shaped" Tetracarboxylate Ligands: Synthesis, Crystal Structures, "naked-Eye" Luminescent Detection, and Catalytic Properties
Wu, Pengyan,Xia, Lingling,Huangfu, Mengjie,Fu, Fubin,Wang, Mengqiu,Wen, Bingxin,Yang, Ziyun,Wang, Jian
, p. 264 - 273 (2020)
Three lanthanide-based metal-organic frameworks, [Tb(HMDIA)(H2O)3]·H2O (Tb-MDIA), [Ho(HMDIA)(H2O)3]·(H2O)2 (Ho-MDIA), and [Nd(HMDIA)(H2O)3]·(H2O)
O,N-Heterocyclic germylenes as efficient catalysts for hydroboration and cyanosilylation of benzaldehyde
Arsenyeva, Kseniya V.,Pashanova, Kira I.,Trofimova, Olesya Yu.,Ershova, Irina V.,Chegerev, Maxim G.,Starikova, Alyona A.,Cherkasov, Anton V.,Syroeshkin, Mikhail A.,Kozmenkova, Anna Ya.,Piskunov, Alexandr V.
, p. 11758 - 11767 (2021/07/12)
New monomeric O,N-heterocyclic germylene AdAPGe (1) based on 4,6-di-tert-butyl-N-adamantyl-o-aminophenol is synthesized and structurally characterized. Germylene 1 in the crystal demonstrates weak Ge?Ge interactions between adjacent molecules. The redox activity of compound 1 and its known analogs PhAPGe (2), t-BuAPGe (3) was studied using cyclic voltammetry and chemical oxidation by the phenoxy radical. Germylene 1, as opposed to 2 and 3, was found to form a relatively stable o-iminosemiquinonate moiety during oxidation. The last one was detected by EPR spectroscopy in toluene solution at low temperatures. The catalytic activity of germylenes 1-3 and dippAPGe (4) (dipp-2,6-di-isopropylphenyl) towards hydroboration and cyanosilylation of benzaldehyde was examined. Germylene 1 demonstrates the most potent promoter properties for such reactions, which allowed cyanosilylation and hydroboration of aldehyde under mild conditions with excellent conversion quickly. Theoretical studies were performed to establish the mechanism, and different reaction routes were examined. According to the DFT (B3LYP/def2-SVP) calculation, cyanosilylation and hydroboration processes are initiated by coordinating TMSCN or HBpin with the catalyst. The followed reaction with aldehyde leads to the resulting products.
Application of an Electrochemical Microflow Reactor for Cyanosilylation: Machine Learning-Assisted Exploration of Suitable Reaction Conditions for Semi-Large-Scale Synthesis
Sato, Eisuke,Fujii, Mayu,Tanaka, Hiroki,Mitsudo, Koichi,Kondo, Masaru,Takizawa, Shinobu,Sasai, Hiroaki,Washio, Takeshi,Ishikawa, Kazunori,Suga, Seiji
supporting information, p. 16035 - 16044 (2021/09/02)
Cyanosilylation of carbonyl compounds provides protected cyanohydrins, which can be converted into many kinds of compounds such as amino alcohols, amides, esters, and carboxylic acids. In particular, the use of trimethylsilyl cyanide as the sole carbon source can avoid the need for more toxic inorganic cyanides. In this paper, we describe an electrochemically initiated cyanosilylation of carbonyl compounds and its application to a microflow reactor. Furthermore, to identify suitable reaction conditions, which reflect considerations beyond simply a high yield, we demonstrate machine learning-assisted optimization. Machine learning can be used to adjust the current and flow rate at the same time and identify the conditions needed to achieve the best productivity.
Cyanosilylation of carbonyl compounds catalyzed by half-sandwich (η6-p-cymene) Ruthenium(II) complexes bearing heterocyclic hydrazone derivatives
Alves, Luis G.,Bharathi, Madheswaran,Indira, Sekar,Martins, Ana M.,Shanmuga Bharathi, Kuppannan,Vinoth, Govindasamy
, (2020/10/02)
A new class of half-sandwich (?6-p-cymene) ruthenium(II) complexes supported by heterocyclic hydrazone derivatives of general formula [Ru(?6-p-cymene)(Cl)(L)] where L represents N’-((1H-pyrrol-2-yl)methylene)furan-2-carbohydrazide (L
