26118-61-6Relevant articles and documents
A Rotaxane Scaffold for the Construction of Multiporphyrinic Light-Harvesting Devices
Delavaux-Nicot, Béatrice,Ben Aziza, Haifa,Nierengarten, Iwona,Minh Nguyet Trinh, Thi,Meichsner, Eric,Chessé, Matthieu,Holler, Michel,Abidi, Rym,Maisonhaute, Emmanuel,Nierengarten, Jean-Fran?ois
, p. 133 - 140 (2018)
A sophisticated photoactive molecular device has been prepared by combining recent concepts for the preparation of multifunctional nanomolecules (click chemistry on multifunctional scaffolds) with supramolecular chemistry (self-assembly to prepare rotaxanes). Specifically, a clickable [2]rotaxane scaffold incorporating a free-base porphyrin stopper has been prepared and functionalized with ten peripheral Zn(II)-porphyrin moieties. Electrochemical investigations of the final compound revealed a peculiar behavior resulting from the intramolecular coordination of the Zn(II) porphyrin moieties to 1,2,3-triazole units. Finally, steady state investigations of the compound combining Zn(II) and free-base porphyrin moieties have shown that this compound is a light-harvesting device capable of channeling the light energy from the peripheral Zn(II)-porphyrin subunits to the core by singlet–singlet energy transfer.
Method for preparing sebacic acid ester and derivatives thereof (by machine translation)
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Paragraph 0064-0072; 0095; 0098-0135, (2020/05/01)
. Uses the compound of the formula, as the raw material, in the acid solvent selective hydrodeoxygenation to obtain.decanediol and n-decanol: and the method (I) is characterized in that the product is cheap and easily available, product in yield, high in purity, and suitable for industrial production 1,10 - in a simple, process route . The product obtained by the method has the advantages of high yield, high yield and low pollution, to the environment, and the corresponding alcohol, is obtained by saponification reaction. (by machine translation)
Molecular iodine in isopropenyl acetate (IPA): a highly efficient catalyst for the acetylation of alcohols, amines and phenols under solvent free conditions
Ahmed, Naseem,van Lier, Johan E.
, p. 5345 - 5349 (2007/10/03)
Iodine in isopropenyl acetate (IPA) is a highly efficient catalyst for the acetylation of a variety of alcohols, phenols and amines under solvent free conditions. Primary, secondary, tertiary alcohols, amines and mono to polyhydroxy phenols and anilines with electron donating or withdrawing substituents can be easily acetylated in good to excellent yield at 85-90 °C.