39654-03-0

Basic information

• Product Name: (p-Chlorphenyl)-aethinyl-p-methylphenyl-sulfid
• Synonyms: (p-Chlorphenyl)-aethinyl-p-methylphenyl-sulfid
• CAS NO: 39654-03-0
• Molecular Weight: 258.771
• Mol File: 39654-03-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (p-Chlorphenyl)-aethinyl-p-methylphenyl-sulfid(CAS DataBase Reference)
• NIST Chemistry Reference: (p-Chlorphenyl)-aethinyl-p-methylphenyl-sulfid(39654-03-0)
• EPA Substance Registry System: (p-Chlorphenyl)-aethinyl-p-methylphenyl-sulfid(39654-03-0)

Safety Data

• Hazardous Substances Data: 39654-03-0(Hazardous Substances Data)

Upstream product

• 33491-02-0 1-chloro-4-(chloroethynyl)benzene 
• 10486-08-5 sodium p-thiocresolate 
• 106-45-6 para-thiocresol 
• 873-73-4 4-n-chlorophenylacetylene 
• 77295-59-1 1-chloro-4-(2,2-dibromovinyl)benzene 
• 33491-03-1 1-(bromoethynyl)-4-chlorobenzene 

Relevant articles and documents

Transition Metal-Free C-H Thiolation via Sulfonium Salts Using β-Sulfinylesters as the Sulfur Source

We disclose a direct C(sp)-, C(sp2)-, and C(sp3)-H thiolation reaction using β-sulfinylesters as the versatile sulfur source. The key step of this protocol is chemoselective C-S bond cleavage of the sulfonium salts that are formed in situ from the corresponding alkenes, alkynes, and 1,3-dicarboxyl compounds with β-sulfinylesters. The successful capture of the acrylate byproduct supports a retro-Michael reaction mechanism.