557087-01-1

Basic information

• Product Name: 2-dimethylamino-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: 2-dimethylamino-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• CAS NO: 557087-01-1
• Molecular Weight: 171.047
• Mol File: 557087-01-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-dimethylamino-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-dimethylamino-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(557087-01-1)
• EPA Substance Registry System: 2-dimethylamino-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(557087-01-1)

Safety Data

• Hazardous Substances Data: 557087-01-1(Hazardous Substances Data)

Upstream product

• 611-74-5 N,N-dimethylbenzamide 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 1137-79-7 N,N-dimethyl-4-biphenylamine 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 269410-08-4 pyrazole-4-boronic acid pinacol ester 
• 69190-62-1 pinacol butylboronate 
• 338998-93-9 4,4,5,5-tetramethyl-2-(5-methylfuran-2-yl)-1,3,2-dioxaborolane 
• 452972-15-5 4-chloro-3-( 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 
• 936618-92-7 2-(3-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 1117-37-9 ethyl (E)-3-(dimethylamino)acrylate 
• 85118-28-1 3-Dimethylamino-buttersaeureethylester 
• 33598-36-6 methyl 3-dimethylamino-n-butyrate 
• 24686-81-5 β-Dimethylamino-β-phenylpropiophenone 
• 24686-80-4 4-Dimethylamino-4-phenyl-butan-2-one 
• 3506-56-7 3-(dimethylamino)-1-phenylbutan-1-one 

Relevant articles and documents

Photoinduced Deaminative Borylation of Unreactive Aromatic Amines Enhanced by CO2

Herein, direct unreactive C-N borylation of aromatic amines by a photocatalyst was achieved. The C-N borylation of aromatic amines with bis(pinacolato)diboron (B2pin2) proceeded using a pyrene catalyst under light irradiation to afford desired borylated products and aminoborane as a byproduct. The yield of the borylated product improved under a CO2 atmosphere which probably reduced the inhibitory effect of aminoborane. Mechanistic studies suggested that the C-N bond cleavage and C-B bond formation proceeded via a concerted pathway.