60147-30-0

Basic information

• Product Name: 10,13,16-tris(p-tolylsulphonyl)-1,4,7-trioxa-10,13,16-triazacyclo-octadecane
• CAS NO: 60147-30-0
• Molecular Weight: 723.933
• Mol File: 60147-30-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 10,13,16-tris(p-tolylsulphonyl)-1,4,7-trioxa-10,13,16-triazacyclo-octadecane(CAS DataBase Reference)
• NIST Chemistry Reference: 10,13,16-tris(p-tolylsulphonyl)-1,4,7-trioxa-10,13,16-triazacyclo-octadecane(60147-30-0)
• EPA Substance Registry System: 10,13,16-tris(p-tolylsulphonyl)-1,4,7-trioxa-10,13,16-triazacyclo-octadecane(60147-30-0)

Safety Data

• Hazardous Substances Data: 60147-30-0(Hazardous Substances Data)

Upstream product

• 56187-04-3 1,4,7-tritosyl-1,4,7-triazaheptane 
• 31255-26-2 1-bromo-2-{2-[2-(2-bromoethoxy)ethoxy]-ethoxy}ethane 
• 59945-35-6 N,N'-((ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl))bis(4-methylbenzenesulfonamide) 
• 37860-51-8 tetraethylene glycol di(p-toluenesulfonate) 
• 98-59-9 p-toluenesulfonyl chloride 
• 112-60-7 Tetraethylene glycol 
• 70-55-3 toluene-4-sulfonamide 
• 16695-22-0 N,N-bis(tosyloxyethyl)-p-toluenesulfonamide 
• 59945-36-7 1,11-bis(p-tolylsulphonylamino)-3,6,9-trioxaundecane 
• 52601-80-6 N,N’,N”-tris(p-toluenesulfonyl)diethylenetriamine N,N-disodium salt 

Relevant articles and documents

Synthesis and Separating Properties of Tris(Merrifield Peptide Resin)

A triazacrown ion exchanger, 1,13,16-trioxa-4,7,10-triazacyclooctadecane (TOTA)-4,7,10-tris(Merrifield peptide resin) was synthesized. This resin has a capacity of 0.1 meq/g dry resin. The resin was used for the elution chromatographic separation of lithi

MACROHETEROCYCLES. PART 44. FACILE SYNTHESIS OF AZACROWN ETHERS AND CRYPTANDS IN A TWO-PHASE SYSTEM

A facile procedure is proposed for the preparation of azacrown ethers and cryptands by condensation of dibromides or ethylene glycol bis(toluene-p-sulphonate)s with acyclic bis(sulphonamide)s or with bisdiazacrown ethers, respectively.The reaction was carried out in a two-phase system of aqueous alkali-toluene (benzene)in the presence of quaternary ammonium salts as phase transfer catalysts.The catalytic activity decreased in the sequence: Bu4NI ca.Bu4NBr > Bu4NCl > Bu4NHSO4 > Et3NCH2C6H5NCl.Maximum yields of twelve-membered azacrown ethers are obtained when lithium hydroxide is used, while crown ethers of larger size are observed in the presence of sodium or potassium hydroxides; this may be due to a template effect.