6069-38-1

Basic information

• Product Name: 1,3-DIMETHYL-2-DIMETHYLAMINO-1,3,2-DIAZAPHOSPHOLIDINE
• Synonyms: 1,3,2-Diazaphospholidin-2-amine,N,N,1,3-tetramethyl-;1,3,2-Diazaphospholidine, 1,3-dimethyl-2-dimethylamino-;1,3-DIMETHYL-2-DIMETHYLAMINO-1,3,2-DIAZAPHOSPHOLIDINE
• CAS NO: 6069-38-1
• Molecular Formula: C₆H₁₆N₃P
• Molecular Weight: 161.185101
• Mol File: 6069-38-1.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 171.8°Cat760mmHg
• Flash Point: 57.7°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 1.37mmHg at 25°C
• CAS DataBase Reference: 1,3-DIMETHYL-2-DIMETHYLAMINO-1,3,2-DIAZAPHOSPHOLIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-DIMETHYL-2-DIMETHYLAMINO-1,3,2-DIAZAPHOSPHOLIDINE(6069-38-1)
• EPA Substance Registry System: 1,3-DIMETHYL-2-DIMETHYLAMINO-1,3,2-DIAZAPHOSPHOLIDINE(6069-38-1)

Safety Data

• Hazardous Substances Data: 6069-38-1(Hazardous Substances Data)

Usage

Type of compound

Organophosphorus compound

Structural feature

Contains a diazaphospholidine ring

Usage

a. Organic synthesis
b. Catalysis as a chiral ligand for transition metal complexes

Potential applications

a. Medicinal chemistry
b. Building block for the synthesis of other biologically active compounds

Handling requirements

Careful handling and specialized knowledge due to complex structure and potential reactivity

InChI:InChI=1/C6H16N3P/c1-7(2)10-8(3)5-6-9(10)4/h5-6H2,1-4H3

Upstream product

• 6069-36-9 2-chloro-1,3-dimethyl-1,3,2-diazaphospholidine 
• 124-40-3 dimethyl amine 
• 110-70-3 N,N`-dimethylethylenediamine 
• 1608-26-0 Hexamethylphosphorous triamide 

Downstream Products

• 7137-86-2 2-methoxy-1,3-dimethyl-1,3,2-diazaphospholane 
• 20303-02-0 5-dimethylamino-6,9-dimethyl-2r,3t-diphenyl-2,3c-bis-trifluoromethyl-1,4-dioxa-6,9-diaza-5λ⁵-phospha-spiro[4.4]nonane 
• 7137-89-5 5-dimethylamino-6,9-dimethyl-2,3-diphenyl-1,4-dioxa-6,9-diaza-5λ⁵-phospha-spiro[4.4]non-2-ene 
• 56642-17-2 5-dimethylamino-2,6,9-trimethyl-3-phenyl-1,4-dioxa-6,9-diaza-5λ⁵-phospha-spiro[4.4]non-2-ene 
• 56642-25-2 8-acetyl-5-dimethylamino-1,4,7-trimethyl-9-phenyl-6-oxa-1,4-diaza-5λ⁵-phospha-spiro[4.4]non-7-ene 
• 6069-40-5 dimethylamino-2,dimethyl-1,3,phenylimino-2,diazaphospholane-3,2 
• 699023-75-1 (E)-(R)-(1,3-dimethyl-2-oxo-2λ⁵-[1,3,2]diazaphospholidin-2-yl)-(1-ethyl-but-2-enyl)-phosphoramidic acid diphenyl ester 
• 699023-69-3 (E)-(R)-N-(1,3-dimethyl-2-oxo-2λ⁵-[1,3,2]diazaphospholidin-2-yl)-N-(1-ethyl-but-2-enyl)-4-methyl-benzenesulfonamide 
• 699023-70-6 (E)-(S)-N-(1,3-dimethyl-2-oxo-2λ⁵-[1,3,2]diazaphospholidin-2-yl)-N-(1-ethyl-but-2-enyl)-4-methyl-benzenesulfonamide 
• 699023-51-3 [1,3-dimethyl-2-(2-methyl-allyloxy)-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene]-phosphoramidic acid diphenyl ester 
• 699023-39-7 N-[1,3-dimethyl-2-(2-methyl-allyloxy)-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene]-4-methyl-benzenesulfonamide 
• 699023-43-3 (E)-N-[1,3-dimethyl-2-(3-phenyl-allyloxy)-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene]-4-methyl-benzenesulfonamide 
• 699023-54-6 (E)-[2-(1-ethyl-but-2-enyloxy)-1,3-dimethyl-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene]-phosphoramidic acid diphenyl ester 
• 699023-49-9 (E)-[1,3-dimethyl-2-(pent-2-enyloxy)-2λ⁵-[1,3,2]diazaphospholidin-2-ylidene]phosphoramidic acid diphenyl ester 

Relevant articles and documents

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EFFICIENT OLEFINATION WITH α-ALKYL CYCLIC PHOSPHONAMIDES

A variety of acyclic and cyclic aldehydes and ketones can be converted into the corresponding alkylidene, benzylidene and methoxycarbonyl alkylidene derivatives by treatment with 1,3,2-diazaphospholidine-2-alkyl-1,3-dimethyl 2-oxides (α-alkyl cyclic phosphonamides) under mild conditions.This olefination method is particularly useful in the case of enolizable carbonyl compounds.