6148-33-0

Basic information

• Product Name: ethyl 2,4-dimethyl-3-furoate
• Synonyms: ethyl 2,4-dimethyl-3-furoate;2,4-Dimethyl-3-furancarboxylic acid ethyl ester;3-Furancarboxylic acid, 2,4-diMethyl-, ethyl ester
• CAS NO: 6148-33-0
• Molecular Formula: C₉H₁₂O₃
• Molecular Weight: 168.19
• Mol File: 6148-33-0.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ethyl 2,4-dimethyl-3-furoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2,4-dimethyl-3-furoate(6148-33-0)
• EPA Substance Registry System: ethyl 2,4-dimethyl-3-furoate(6148-33-0)

Safety Data

• RIDADR: 1993
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 6148-33-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 73, p. 356, 1951 DOI: 10.1021/ja01145a119

Upstream product

• 35044-52-1 ethyl 2-acetyl-3-methylbut-2-enoate 
• 1609547-45-6 ethyl 2,4-dimethyl-4,5-dihydrofuran-3-carboxylate 
• 15301-37-8 3-ethoxycarbonyl-3-penten-2-one 
• 4341-76-8 Ethyl 2-butynoate 
• 855369-97-0 C₉H₁₄O₄ 
• 22157-28-4 3-methoxy-2(E)-butenoic acid ethyl ester 
• 141-97-9 ethyl acetoacetate 
• 141764-75-2 2-Acetyl-4-benzenesulfinyl-3-methyl-butyric acid ethyl ester 
• 78-95-5 chloroacetone 
• 692-72-8 3-acetoxy-2-chloroprop-1-ene 
• 627-09-8 Propargyl acetate 
• 141764-81-0 2,4-Dimethyl-5-phenylsulfanyl-4,5-dihydro-furan-3-carboxylic acid ethyl ester 
• 122552-44-7 2-Bromo-3-methoxy-3-prop-2-ynyloxy-butyric acid ethyl ester 
• 96-11-7 1,2,3-tribromopropane 

Downstream Products

• 79204-37-8 2,4-dimethyl-3-furylmethyl benzoate 
• 114567-30-5 4-(2,4-Dimethyl-furan-3-ylmethyl)-5-methyl-benzene-1,3-diol 
• 114567-31-6 2-(2,4-Dimethyl-furan-3-ylmethyl)-5-methyl-benzene-1,3-diol 

Relevant articles and documents

Reactions of ethyl diazoacetate with β-methylfurans

Reactions of β-methylfuran and 2,4-dimethylfuran with ethyl diazoacetate in the presence of [Rh2(OAc)4] catalyst, followed by iodine- induced isomerization, yielded furan ring-unravelled products. The results are compared with those of α-methylfurans.

Isotetronic acids from an oxidative cyclization

Oxidation of α,β-unsaturated methyl ketones with selenium dioxide leads to a cascade of reactions culminating in the formation of isotetronic acids.

CuO/CNTs-catalyzed heterogeneous process: A convenient strategy to prepare furan derivatives from electron-deficient alkynes and α-hydroxy ketones

As heterogeneous catalysts and nanoparticle support materials, CNTs have attracted great interest in organic chemistry. This paper reports facile CuO/CNTs-catalyzed cyclization to form furan derivatives from electron-deficient alkynes and α-hydroxy ketones. It represents a facile synthetic route, and the eco-friendly catalyst can be easily separated by filtration and reused.