6469-85-8

Basic information

• Product Name: 2-(4-chlorophenylthio)benzoic acid
• Synonyms: 2-(4-chlorophenylthio)benzoic acid;o-(p-Chlorophenylthio)benzoic acid
• CAS NO: 6469-85-8
• Molecular Formula: C₁₃H₉ClO₂S
• Molecular Weight: 264.72736
• EINECS: 229-287-2
• Mol File: 6469-85-8.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 421.1°C at 760 mmHg
• Flash Point: 208.5°C
• Appearance: /
• Density: 1.42g/cm³
• Vapor Pressure: 7.61E-08mmHg at 25°C
• Refractive Index: 1.683
• CAS DataBase Reference: 2-(4-chlorophenylthio)benzoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-chlorophenylthio)benzoic acid(6469-85-8)
• EPA Substance Registry System: 2-(4-chlorophenylthio)benzoic acid(6469-85-8)

Safety Data

• Hazardous Substances Data: 6469-85-8(Hazardous Substances Data)

Usage

General Description

2-(4-chlorophenylthio)benzoic acid is a chemical compound with the molecular formula C13H9ClOS. It is a derivative of benzoic acid and contains a chlorine-substituted phenyl group attached to a thioether group. 2-(4-chlorophenylthio)benzoic acid is widely used as a intermediate in the synthesis of pharmaceuticals, agrochemicals, and other organic compounds. It also has potential applications in the field of materials science and drug discovery. Additionally, it has been studied for its antimicrobial and antifungal properties, making it a compound of interest in the development of new antimicrobial agents.

InChI:InChI=1/C13H9ClO2S/c14-9-5-7-10(8-6-9)17-12-4-2-1-3-11(12)13(15)16/h1-8H,(H,15,16)

Upstream product

• 41932-36-9 4-{[2-(4-chloro-phenylsulfanyl)-phenyl]-oxo-thioacetyl}-morpholine 
• 106-54-7 p-Chlorothiophenol 
• 88-65-3 2-bromobenzoic-acid 
• 106-46-7 para-dichlorobenzene 
• 72433-38-6 2-(4'-chloro-phenylthio)-benzonitrile 
• 109-86-4 2-methoxy-ethanol 
• 118-91-2 ortho-chlorobenzoic acid 
• 6469-86-9 2-<4-Chlor-phenylthio>-benzoesaeurechlorid 
• 41932-35-8 1-[2-(4-chloro-phenylsulfanyl)-phenyl]-ethanone 
• 88-67-5 2-Iodobenzoic acid 
• 653589-95-8 2-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid methyl ester 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 1146-44-7 4,4'-dichlorophenyl thiosulfonate 
• 22096-70-4 4-chlorophenyl 2-methoxycarbonylphenyl sulfide 

Downstream Products

• 13459-59-1 (2-(4-chlorophenylthio)phenyl)methanol 
• 144463-75-2 allyl 2-(4-chlorothiophenoxy)benzoate 
• 108475-21-4 2-(4-chloro-phenylsulfanyl)-benzoic acid ethyl ester 
• 22096-70-4 4-chlorophenyl 2-methoxycarbonylphenyl sulfide 
• 86-39-5 2-Chlorothioxanthone 

Relevant articles and documents

Identification of 2-chlorothioxanthen-9-one in gastric aspirate in a case of chlorprothixene poisoning

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COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND AN ELECTRONIC DEVICE THEREOF

The present invention relates to a compound for an organic electronic element. To the present invention, an organic electronic element having high luminous efficiency, low driving voltage, and high heat resistance can be provided, and color purity and lifetime of the organic electronic element can be improved.

Carboxyl radical-assisted 1,5-aryl migration through Smiles rearrangement

We report herein, a silver(i)-catalyzed Smiles rearrangement of 2-aryloxy- or 2-(arylthio)benzoic acids to provide aryl-2-hydroxybenzoate or aryl-2-mercaptobenzoate dimer, respectively, through 1,5-aryl migration from oxygen or sulfur to carboxylate oxygen. Mechanistically, the aryl ether moiety undergoes an intramolecular ipso attack by the carboxyl radical followed by a C-O or C-S bond cleavage. Aryl-2-mercaptobenzoates undergo oxidative dimerization through a thiol moiety in situ.