65826-67-7

Basic information

• Product Name: bis(4-bromophenyl)iodonium bromide
• Synonyms: bis(4-bromophenyl)iodonium bromide
• CAS NO: 65826-67-7
• Molecular Weight: 518.812
• Mol File: 65826-67-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: bis(4-bromophenyl)iodonium bromide(CAS DataBase Reference)
• NIST Chemistry Reference: bis(4-bromophenyl)iodonium bromide(65826-67-7)
• EPA Substance Registry System: bis(4-bromophenyl)iodonium bromide(65826-67-7)

Safety Data

• Hazardous Substances Data: 65826-67-7(Hazardous Substances Data)

Upstream product

• 589-87-7 1,4-bromoiodobenzene 
• 108-86-1 bromobenzene 

Downstream Products

• 1318254-95-3 9-(4-bromophenyl)-2,6-dichloro-9H-purine 
• 68716-49-4 p-bromophenylboronic acid pinacol ester 
• 4995-11-3 2-(4-bromophenyl)-1H-pyrrole 
• 589-87-7 1,4-bromoiodobenzene 
• 103185-00-8 1-bromo-4-[¹⁸F]fluorobenzene 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 107411-29-0 1-(4-bromophenyl)-2-methyl-1H-benzo[d]imidazole 
• 502925-12-4 1-(4-bromophenyl)-1H-benzo[d]imidazole 
• 174621-52-4 N-(4-bromophenyl)-1H-indole 
• 20541-48-4 1,2-bis(4-bromophenyl)diselenide 
• 92-86-4 4-(4-bromophenyl)bromobenzene 
• 3988-03-2 bis(4-bromophenyl)methanone 
• 35578-47-3 4,4'-dibromobenzil 
• 87243-31-0 2-(4-bromophenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione 

Relevant articles and documents

A mild carbon-boron bond formation from diaryliodonium salts

The direct metal-free borylation of diaryliodonium salts with diboron reagents is now demonstrated to be a feasible process toward formation of aryl boronic esters without any additive or catalysts, and it can be extended to a two-step C-C coupling of both aryl groups of the initial diaryliodonium reagent.

Facile syntheses of symmetrical diaryliodonium salts from various arenes, with sodium metaperiodate as the coupling reagent in acidic media

An easy, inexpensive, safe, and effective preparative procedure to obtain symmetrical diaryliodonium bromides (in 17-88% crude yields) from various arenes is presented in this paper. A novel method for the in situ preparation of iodosyl sulfate (Chretien's reagent) is given. Eleven exemplary crude diaryliodonium bromides were readily oxidatively metathesized with 40% aqueous tetrafluoroboric acid and 30% aqueous hydrogen peroxide (in boiling acetone, used both as a solvent and 'halogen scavenger') to give pure diaryliodonium tetrafluoroborates in 15-85% yields. Georg Thieme Verlag Stuttgart.