66622-39-7

Basic information

• Product Name: 4-methyl-4-phenylpent-1ene
• Synonyms: 4-methyl-4-phenylpent-1ene
• CAS NO: 66622-39-7
• Molecular Weight: 160.259
• Mol File: 66622-39-7.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: 4-methyl-4-phenylpent-1ene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-4-phenylpent-1ene(66622-39-7)
• EPA Substance Registry System: 4-methyl-4-phenylpent-1ene(66622-39-7)

Safety Data

• Hazardous Substances Data: 66622-39-7(Hazardous Substances Data)

Upstream product

• 4028-23-3 Allylchlorodimethylsilane 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 53317-08-1 9-allyl-9-bora-bicyclo[3.3.1]nonane 
• 935-67-1 Cumyl methyl ether 
• 35466-83-2 allyl methyl carbonate 
• 826-55-1 2-methyl-2-phenylpropionic acid 
• 3575-19-7 2-bromo-2-phenylpropane 
• 24850-33-7 allyltributylstanane 
• 81710-07-8 2,2-dimethyl-5-(1-methyl-1-phenylethyl)-1,3-dioxane-4,6-dione 
• 762-72-1 allyl-trimethyl-silane 
• 3425-72-7 cumyl acetate 
• 1381983-00-1 1,3-diphenyl-2-(2-phenylpropan-2-yl)propane-1,3-dione 
• 1006895-38-0 4-methyl-4-phenyl-penta-1,2-diene 
• 253185-03-4 tert-butylbenzene 

Downstream Products

• 73040-76-3 (4-Bromo-3-ethoxy-1,1-dimethyl-butyl)-benzene 
• 881392-78-5 2-amino-4-methyl-4-phenyl-pentanoic acid 
• 6325-41-3 3-methyl-3-phenylbutanal 

Relevant articles and documents

Organophotoredox/palladium dual catalytic decarboxylative Csp3-Csp3coupling of carboxylic acids and π-electrophiles

A dual catalytic decarboxylative allylation and benzylation method for the construction of new C(sp3)-C(sp3) bonds between readily available carboxylic acids and functionally diverse carbonate electrophiles has been developed. The new process is mild, operationally simple, and has greatly improved upon the efficiency and generality of previous methodology. In addition, new insights into the reaction mechanism have been realized and provide further understanding of the harnessed reactivity.

Carbon-based leaving group in substitution reactions: Functionalization of sp3-hybridized quaternary and tertiary benzylic carbon centers

Lewis acid promoted substitution reactions employing Meldrum's acid and 5-methyl Meldrum's acid as carbon-based leaving groups are described which transform unstrained quaternary and tertiary benzylic Csp 3-Csp3 bonds into Csp3-X bonds (X = C, H, N). Importantly, this reaction has a broad scope in terms of both suitable substrates and nucleophiles with good to excellent yields obtained (typically >90%).

Indium(i)-catalyzed alkyl-allyl coupling between ethers and an allylborane

An efficient method for alkyl-allyl cross-coupling between ethers and a 9-BBN-derived allylborane catalyzed by indium(i) triflate has been developed. The allylborane proved to be essential to obtain the desired products in high yields. The reaction displayed good substrate scope including high functional group tolerance. The Royal Society of Chemistry 2011.