69447-36-5

Basic information

• Product Name: Diselenide, bis(2-methylphenyl)
• CAS NO: 69447-36-5
• Molecular Formula: C14H14Se2
• Molecular Weight: 340.185
• Mol File: 69447-36-5.mol
• Article Data: 27

Chemical Properties

• CAS DataBase Reference: Diselenide, bis(2-methylphenyl)(CAS DataBase Reference)
• NIST Chemistry Reference: Diselenide, bis(2-methylphenyl)(69447-36-5)
• EPA Substance Registry System: Diselenide, bis(2-methylphenyl)(69447-36-5)

Safety Data

• Hazardous Substances Data: 69447-36-5(Hazardous Substances Data)

Upstream product

• 37773-21-0 2-methylbenzeneselenol 
• 932-31-0 ortho-tolylmagnesium bromide 
• 16419-60-6 2-Methylphenylboronic acid 
• 615-37-2 ortho-methylphenyl iodide 
• 56504-42-8 bis(phenylsulfonyl) diselenide 
• 2093-46-1 2-methylphenyl diazonium tetrafluoroborate 
• 51694-20-3 1-methyl-2-selenocyanatobenzene 

Downstream Products

• 1093647-24-5 C₁₉H₂₃NOSe 
• 1190439-52-1 C₂₀H₂₃NO₃Se 
• 1415931-35-9 C₁₆H₁₂ClNSe 
• 1422738-90-6 (E)-1,2-diphenyl-1,2-bis(o-tolylselenyl)ethene 
• 1436860-93-3 ? 2-(o-tolylselanyl)pyridine 
• 1528-88-7 2-methylphenyl methyl selenide 
• 1041465-95-5 (E)-(styryl)(2-methyl-phenyl)selenide 

Relevant articles and documents

Green preparation method of aryl diselenium ether type organic selenium compound

The invention discloses an aryl diselenium ether compound synthesis method. The synthesis method comprises the following steps: taking the compound represented by the formula (I) as a reaction raw material, CuBr as a catalyst, KOH in the condition Se, a reducing agent, a disproportionation reaction, water or ethanol as a solvent, and 60 °C. After completion of the reaction, the obtained reaction solution is subjected to post-treatment (if ethanol is recovered as solvent) to obtain the aryl diselenoether compound represented by the formula (II), the yield is close 100%, the subsequent treatment is simple, and a complex separation and purification method is not needed to obtain a pure product. The solvent is recovered as a solvent such as ethanol. , It is preferable. The method is more green. Economy, high efficiency, environmental protection.

Metal-free synthesis of unsymmetrical selenides from pyridinium salts and diselenides catalysed by visible light

We report the first metal-free selenolations of pyridinium salts with diselenides to prepare unsymmetrical organoselenides catalysed by visible light. This protocol is an efficient and green method for the preparation of unsymmetrical organoselenides because metal-free conditions and readily accessible diselenides are used.

Visible Light-Promoted Selenylation/Cyclization of Enaminones toward the Formation of 3-Selanyl-4H-Chromen-4-Ones

A simple and efficient visible-light-promoted selenylation/cyclization of enaminones have been realized for the practical synthesis of 3-selanyl-4H-chromen-4-ones. This reaction is performed in the mild conditions, no transition metal catalyst or photocatalysts and no additional oxidants are required. In addition, the 3-selanyl-4H-chromen-4-ones could be easily converted to selanyl-functionalized pyrimidines by reacting with benzamidine substrates. (Figure presented.).