71867-96-4Relevant articles and documents
Monosubstituted and polysubstituted functional group aromatic ketone compounds, and preparation method and photopolymerization initiator thereof
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Paragraph 0046-0050, (2022/01/08)
The invention belongs to the field of radiation curing new materials, and relates to an aromatic ketone compound, in particular to a monosubstituted or polysubstituted polyfunctional group aromatic ketone compound, a preparation method thereof and a photopolymerization composition containing an ethylenically unsaturated compound system, which takes the compound as an effective component. The invention provides monosubstituted and polysubstituted polyfunctional group aromatic ketone compounds. The polyfunctional group aromatic ketone compounds have a general formula structure as shown in (I). The invention also discloses a preparation method and an application of the polyfunctional aromatic ketone compound. According to the invention, industrial-grade raw materials which are low in cost and easy to obtain are used as a starting point to prepare the monosubstituted or polysubstituted functionalized aromatic ketone compound in a breakthrough way, and the compound is applied to a photoinitiator in radiation curing, so that the problems of toxicity and VOCs pollution of the photoinitiator are solved, and the economic competitiveness of the photoinitiator is strived; the overall cost is reduced, and the photo-initiation efficiency is improved.
Halogen-bonded iodonium ion catalysis: A route to α-hydroxy ketones: Via domino oxidations of secondary alcohols and aliphatic C-H bonds with high selectivity and control
Guha, Somraj,Kazi, Imran,Mukherjee, Pranamita,Sekar, Govindasamy
, p. 10942 - 10945 (2017/10/13)
A domino synthesis of α-hydroxy ketones has been developed from benzylic secondary alcohols employing catalytic iodonium ions stabilized by DMSO. The reaction proceeds through an unprecedented sequential oxidation of alcohols to ketone and its α-hydroxylation in a controlled manner. The spectroscopic evidence establishes the possibility of formation of a stable halogen-bonded adduct between DMSO and iodonium ions.
I2- or NBS-catalyzed highly efficient α-hydroxylation of ketones with dimethyl sulfoxide
Liang, Yu-Feng,Wu, Kai,Song, Song,Li, Xinyao,Huang, Xiaoqiang,Jiao, Ning
supporting information, p. 876 - 879 (2015/04/14)
An efficient method for the direct preparation of high synthetic valuable α-hydroxycarbonyls is described. The simple and readily available I2 or NBS was used as catalyst. DMSO acts as the oxidant, oxygen source, and solvent. A diverse range of tertiary Csp3-H bonds as well as more challenging secondary Csp3-H bonds could be hydroxylated in this transformation. The reaction is mild, less toxic and easy to perform.