7332-98-1

Basic information

• Product Name: Benzeneacetic acid, a-oxo-, 1,1-dimethylethyl ester
• CAS NO: 7332-98-1
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 7332-98-1.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-oxo-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-oxo-, 1,1-dimethylethyl ester(7332-98-1)
• EPA Substance Registry System: Benzeneacetic acid, a-oxo-, 1,1-dimethylethyl ester(7332-98-1)

Safety Data

• Hazardous Substances Data: 7332-98-1(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 100-58-3 phenylmagnesium bromide 
• 630-19-3 pivalaldehyde 
• 611-73-4 Benzoylformic acid 
• 536-74-3 phenylacetylene 
• 75-65-0 tert-butyl alcohol 
• 614-21-1 2-nitroacetophenone 
• 75-91-2 tert.-butylhydroperoxide 
• 1074-12-0 phenylglyoxal hydrate 
• 1603-79-8 phenylglyoxylic acid ethyl ester 
• 1907-33-1 lithium tert-butoxide 
• 78782-17-9 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane 
• 865-48-5 sodium t-butanolate 
• 492-38-6 2-phenylacrylic acid 

Downstream Products

• 33147-23-8 3-Methyl-2-phenyl-but-2-enoic acid tert-butyl ester 
• 4768-43-8 (R)-α-hydroxyphenylacetic acid tert-butyl ester 
• 4768-43-8 tert-butyl (S)-2-hydroxy-2-phenylacetate 
• 100-52-7 benzaldehyde 
• 611-73-4 Benzoylformic acid 
• 117356-18-0 β-hydroxy β-phenyl acetate de t-butyle 
• 648424-78-6 (R)-tert-butyl 2-hydroxy-2-phenylpropanoate 
• 885316-13-2 (S)-tert-butyl 2-hydroxy-2-phenylpropanoate 
• 1282521-77-0 C₂₄H₂₅O₆P 
• 1070237-63-6 (Z)-tert-butyl 3-nitro-2-phenylacrylate 
• 1133466-69-9 1-tert-butyl 3-methyl (S)-2-hydroxy-2-phenylmalonate 

Relevant articles and documents

Visible-Light-Enabled Paternò-Büchi Reaction via Triplet Energy Transfer for the Synthesis of Oxetanes

One of the most efficient ways to synthesize oxetanes is the light-enabled [2 + 2] cycloaddition reaction of carbonyls and alkenes, referred to as the Paternò-Büchi reaction. The reaction conditions for this transformation typically require the use of hig

Iron-Catalyzed Cleavage Reaction of Keto Acids with Aliphatic Aldehydes for the Synthesis of Ketones and Ketone Esters

The radical–radical coupling reaction is an important synthetic strategy. In this study, the iron-catalyzed radical–radical cross-coupling reaction based on the decarboxylation of keto acids and decarbonylation of aliphatic aldehydes to obtain valuable aryl ketones is reported for the first time. Remarkably, when tertiary aldehydes were used as carbonyl sources, ketone esters were selectively obtained instead of ketones. The gram-scale preparation of aryl ketone through this strategy was easily achieved by using only 3 mol % of the iron catalyst. As a proof-of-concept, the bioactive molecule flurprimidol was synthesized in two steps by using this strategy.

Cobalt-Catalyzed Transfer Hydrogenation of α-Ketoesters and N-Cyclicsulfonylimides Using H2O as Hydrogen Source

A Co-catalyzed effective transfer hydrogenation of various α-ketoesters and N-cyclicsulfonylimides by safe and environmentally benign H2O as hydrogen source is described. The reaction used easily available and easy to handle zinc metal as a reductant. Interestingly, the catalytic system does not require ligand for reduction of N-cyclicsulfonylimides. (Figure presented.).