75158-95-1Relevant articles and documents
An aryl to imidoyl palladium migration process involving intramolecular C-H activation
Zhao, Jian,Yue, Dawei,Campo, Marino A.,Larock, Richard C.
, p. 5288 - 5295 (2008/02/02)
Biologically interesting fluoren-9-one and xanthen-9-one derivatives have been prepared by a novel aryl to imidoyl palladium migration, followed by intramolecular arylation. The fluoren-9-one synthesis appears to involve both a palladium migration mechanism and a C-H activation process proceeding through an unprecedented organopalladium(IV) hydride intermediate. The results from deuterium labeling experiments are consistent with the proposed dual mechanism.
Synthesis of Phosphonic Analogues of Morphactines
Gancarz, R.,Wieczorek, J. S.
, p. 213 - 222 (2007/10/02)
9-Aminofluorenphosphonsaeuren (Morphaktine) entstehen durch Addition von Diethylphosphit an 9-Imino-fluorenderivate.Die primaer erhaltenen Ester werden zu den korrespondierenden Saeuren hydrolysiert, eine Reihe der Aminophosphonsaeuren zerfallen unter den
