909395-03-5Relevant articles and documents
A tether controlled exo-selective trans-annular Diels - Alder (TADA) reaction
Felzmann, Wolfgang,Arion, Vladimir B.,Mieusset, Jean-Luc,Mulzer, Johann
, p. 3849 - 3851 (2006)
A fully substrate controlled stereoselective route to construct cis-hexahydronaphthalene 4 is described starting from nonracemic butenolide 6. The key step is an exo-selective transannular Diels-Alder reaction (TADA) of tetraene 5, whose intrinsic constra