Oxidation of ISOSAFROLE (cas 120-58-1) by sodium hypochlorite catalysed by manganese porphyrins: Unusual competition between epoxidation and O-dealkylation
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Add time:09/05/2019 Source:sciencedirect.com
ISOSAFROLE (cas 120-58-1) (1a) and isoeugenol methyl ether (1b), two closely related substrates, behave very differently when subjected to manganese porphyrins catalysed epoxidation by sodium hypochlorite. A possible explanation is given, in terms of an unusual competition between the epoxidation and the O-dealkylation of the OCH2O moiety.
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