Stannane, diethyldiphenyl-

Base Information

• Chemical Name: Stannane, diethyldiphenyl-
• CAS No.: 10203-52-8
• Molecular Formula: C16H20 Sn
• Molecular Weight: 331.045
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID40144538
• Mol file: 10203-52-8.mol

Synonyms:Stannane, diethyldiphenyl-;10203-52-8;Diethyldiphenylstannane;diethyl(diphenyl)stannane;DIPHENYLDIETHYLTIN;starbld0008709;C16H20Sn;C16-H20-Sn;DTXSID40144538;BTMSMSMZBPEFLD-UHFFFAOYSA-N;Stannane, diethyl-, di(phenyl)-;AKOS030255017

Chemical Property of Stannane, diethyldiphenyl-

Chemical Property:

• Vapor Pressure: 0.000168mmHg at 25°C
• Boiling Point: 340.6°Cat760mmHg
• Flash Point: 164.1°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 3.28940
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 332.058703
• Heavy Atom Count: 17
• Complexity: 188

Purity/Quality:

98%,99%, ^*data from raw suppliers

Diphenyldiethyltin ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[Sn](CC)(C1=CC=CC=C1)C2=CC=CC=C2
• Uses: Diphenyldiethyltin is an organotin compound that is an environmental pollutant that is present in sediment and sewage sludge.

Technology Process of Stannane, diethyldiphenyl-

There total 8 articles about Stannane, diethyldiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

pentaphenylantimony (2170-05-0) + dichlorodiethylstannane (866-55-7) → diethyl(diphenyl)tin (10203-52-8) + tetraphenylchloroantimony(V) (16894-68-1)

Guidance literature:

In toluene; mixt. of Sb and Sn deriv. in a molar ratio 2:1 was allowed to stand in an evacuated glass ampoule at room temp. for 24 h; crystals of Ph4SbCl filtered off; filtrate evapd; residue chromd. on SiO2; identified by elem. anal.;

Reference yield: 78.5%

ethylmagnesium bromide (925-90-6) + diphenyltin(IV) dichloride (1135-99-5) → diethyl(diphenyl)tin (10203-52-8)

Guidance literature:

In diethyl ether; boiling, 1h;;

DOI:10.1021/ja01359a046

Reference yield: 65.0%

Ethylytterbiumiodid (114687-80-8) + diphenyltin(IV) oxide (2273-51-0) → diethyl(diphenyl)tin (10203-52-8)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; byproducts: [O(YbI)2]; soln. of Yb-compd. addn. (dropwise, under Ar, Schlenk flask) with Sn-compd., stirring (2-3 h), aq. HCl addn., extraction (ether), extracts drying (MgSO4);

upstream raw materials:

diethyl tin

diphenylmercury(II)

ethylmagnesium bromide

pentaphenylantimony

Downstream raw materials:

N-[chlorodiethylstannyl]-N-(trimethylsilyl)benzenesulfonamide

dichlorodiethylstannane

diethylphenylstannyl chroride

diethyl-phenyl tin (1+); acetate

Refernces

• 1、 Sharutin,Sharutina,Senchurin,Kovaleva,Shcherbakov,Gladyshev. "Arylation of organotin halides with pentaarylantimony and pentaphenylbismuth". . p. 64 - 65. Retrieved 2007/10/03.
• 2、 Das, V. G. Kumar,Mun, Lo Kong,Blunden, Stephen J.. "Studies on C-heterocyclic tin compounds. The synthesis and spectral characterization of some thienyl tetraorganotin(IV) compounds". . p. 307 - 322. Retrieved 2007/10/02.