Triethylindium

Base Information

• Chemical Name: Triethylindium
• CAS No.: 923-34-2
• Molecular Formula: C6H15 In
• Molecular Weight: 202.005
• Hs Code.: 2931900090
• European Community (EC) Number: 213-095-0
• DSSTox Substance ID: DTXSID1061281
• Wikipedia: Triethylindium
• Wikidata: Q4463329
• Mol file: 923-34-2.mol

Synonyms:Triethylindium;triethylindigane;Indium, triethyl-;923-34-2;EINECS 213-095-0;C6H15In;C6-H15-In;DTXSID1061281;MFCD00015098;AKOS015914856;FT-0658403;A844201;Q4463329

Chemical Property of Triethylindium

Chemical Property:

• Melting Point: -31.9°C
• Refractive Index: 1.5380
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.92170
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 202.0212543
• Heavy Atom Count: 7
• Complexity: 25.7

Purity/Quality:

98% ^*data from raw suppliers

TRIETHYLINDIUM 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: CC[In](CC)CC

Technology Process of Triethylindium

There total 10 articles about Triethylindium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

([(2,6-i-Pr2-C6H3)NC(Me)]2CH)Ga(Et)InEt2 → indium (7440-74-6) + ([(2,6-i-Pr2-C6H3)NC(Me)]2CH)GaEt2 + Triethylindium (923-34-2)

Guidance literature:

In toluene; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.5b00302

Reference yield: 69.0%

(Et3In)2*diphos → Triethylindium (923-34-2)

Guidance literature:

In neat (no solvent); heated slowly under 1E-2 mmHg in a trap-to-trap distillation apparatus (receiver flask at -196 °C), liberation of Et3In started at 90 °C, rapid liberation at 100-115 °C;;

DOI:10.1016/S0277-5387(00)81226-7

Reference yield: 66.0%

(CH2)5(P(C6H5)2In(C2H5)3)2 → Triethylindium (923-34-2)

Guidance literature:

In neat (no solvent); metal complex decomposed at 120-135°C for 2-3 h;

DOI:10.1016/j.jorganchem.2010.11.044

upstream raw materials:

ethylmagnesium chloride

iododimethylindium(III)

ethyllithium

indium(III) chloride

Downstream raw materials:

indium(III) nitride

3-methyldodecane

Refernces

• 1、 Ganesamoorthy, Chelladurai,Bl?ser, Dieter,W?lper, Christoph,Schulz, Stephan. "Synthesis of Heterobimetallic Group 13 Compounds via Oxidative Addition Reaction of Gallanediyl LGa and InEt3". . p. 2991 - 2996. Retrieved 2015/06/30.
• 2、 Shatunov,Korlyukov,Lebedev,Sheludyakov,Kozyrkin,Orlov, V.Yu.. "The synthesis and deep purification of GaEt3. Reversible complexation of adducts MAlk3 (M = Al, Ga, In; Alk = Me, Et) with phenylphosphines". . p. 2238 - 2251. Retrieved 2011/06/22.