N,N-bis(2-chloroethyl)-1,1,1-trimethylsilanamine

Base Information

• Chemical Name: N,N-bis(2-chloroethyl)-1,1,1-trimethylsilanamine
• CAS No.: 82475-57-8
• Molecular Formula: C7H17Cl2NSi
• Molecular Weight: 214.21
• Mol file: 82475-57-8.mol

Synonyms:

Chemical Property of N,N-bis(2-chloroethyl)-1,1,1-trimethylsilanamine

Chemical Property:

• Vapor Pressure: 0.236mmHg at 25°C
• Boiling Point: 213.7°Cat760mmHg
• Flash Point: 83°C
• Density: 1.02g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-bis(2-chloroethyl)-1,1,1-trimethylsilanamine

There total 1 articles about N,N-bis(2-chloroethyl)-1,1,1-trimethylsilanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

chloro-trimethyl-silane (75-77-4) + N,N-bis(chloro-2-ethyl)amine (334-22-5) → N,N-bis(2-chloroethyl)-1,1,1-trimethylsilylamine (82475-57-8)

Guidance literature:

With triethylamine; In diethyl ether; at 25 ℃; for 15h;

DOI:10.1002/jps.2600710517

Reference yield: 90.0%

carbon dioxide (124-38-9,18923-20-1) + N,N-bis(2-chloroethyl)-1,1,1-trimethylsilylamine (82475-57-8) → O-trimethylsilyl-N,N-bis(2-chloroethyl)carbamate (82475-74-9)

Guidance literature:

With N,N-bis(chloro-2-ethyl)amine; In diethyl ether; pentane; at -10 ℃; for 4h;

DOI:10.1002/jps.2600710517

Reference yield: 71.0%

(SP)-boranyl(cyclohexyl)(methyl)phosphane (263768-78-1,263768-79-2,99670-07-2) + N,N-bis(2-chloroethyl)-1,1,1-trimethylsilylamine (82475-57-8) → (S)-2-(boranyl(cyclohexyl)(methyl)phosphanyl)-N-(2-(boranyl(cyclohexyl)(methyl)phosphanyl)ethyl)ethan-1-amine

Guidance literature:

(S_P)-boranyl(cyclohexyl)(methyl)phosphane; With n-butyllithium; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 0.25h; Inert atmosphere; Schlenk technique;

N,N-bis(2-chloroethyl)-1,1,1-trimethylsilylamine; In tetrahydrofuran; hexane; at 20 ℃; Inert atmosphere; Schlenk technique;

With water; sodium hydrogencarbonate; In tetrahydrofuran; hexane;

DOI:10.1002/adsc.201800433

upstream raw materials:

chloro-trimethyl-silane

N,N-bis(chloro-2-ethyl)amine

Downstream raw materials:

O-trimethylsilyl-N,N-bis(2-chloroethyl)carbamate

bis[2-(di-iso-propylphosphino)ethyl]amine

bis(2-(diphenylphosphino)ethyl)amine hydrochloride

bis[2-(dicyclohexylphosphanyl)ethyl]amine

Refernces