2-(Perfluorododecyl)ethyl acrylate

Base Information

• Chemical Name: 2-(Perfluorododecyl)ethyl acrylate
• CAS No.: 34395-24-9
• Molecular Formula: C17H7F25O2
• Molecular Weight: 718.201
• European Community (EC) Number: 251-992-9
• UNII: 3L0TFR8U9Y
• DSSTox Substance ID: DTXSID5067841
• Nikkaji Number: J26.243I
• Wikidata: Q27257475
• Mol file: 34395-24-9.mol

Synonyms:2-(perfluorododecyl)ethyl acrylate;34395-24-9;perfluorododecylethyl acrylate;1,1,2,2-Tetrahydroperfluorotetradecyl acrylate;UNII-3L0TFR8U9Y;3L0TFR8U9Y;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl prop-2-enoate;EINECS 251-992-9;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-Pentacosafluorotetradecyl acrylate;2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl ester;SCHEMBL2462848;DTXSID5067841;C17H7F25O2;(Perfluorododecyl)ethyl 2-propenoate;C17-H7-F25-O2;Acrylic acid 2-(pentacosafluorododecyl)ethyl ester;1H,1H,2H,2H-Pentacosafluorotetradecyl -1-acrylate;Q27257475;ACRYLIC ACID, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-PENTACOSAFLUOROTETRADECYL ESTER

Chemical Property of 2-(Perfluorododecyl)ethyl acrylate

Chemical Property:

• Vapor Pressure: 0.00164mmHg at 25°C
• Refractive Index: 1.311
• Boiling Point: 294.3 °C at 760 mmHg
• Flash Point: 127.7 °C
• PSA: 26.30000
• Density: 1.615 g/cm³
• LogP: 8.65630
• XLogP3: 9.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 27
• Rotatable Bond Count: 15
• Exact Mass: 718.0046835
• Heavy Atom Count: 44
• Complexity: 1070

Purity/Quality:

98%Min ^*data from raw suppliers

2-(PERFLUORODODECYL)ETHYL ACRYLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCCC(C(C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Use Description: 1,1,2,2-Tetrahydroperfluorotetradecyl acrylate is a specialized chemical compound with applications in several fields. In the field of materials science and surface modification, it is utilized as a surface treatment agent or as a component in coatings and films. Its unique fluorinated structure imparts superhydrophobic and oleophobic properties to surfaces, making it valuable for creating water and oil-repellent coatings on various materials, from textiles and electronics to industrial equipment. In the pharmaceutical industry, it may be used in drug delivery systems, particularly for improving the solubility and bioavailability of poorly soluble drugs. Its fluorinated characteristics can aid in the formulation of drugs with enhanced stability and controlled release properties. Furthermore, in academic and industrial research, this compound may be studied for its surface chemistry and reactivity, contributing to advancements in surface science and materials engineering. Its versatile properties make it valuable in materials science, pharmaceuticals, and scientific research, playing a vital role in creating advanced materials and improving drug formulations.

Technology Process of 2-(Perfluorododecyl)ethyl acrylate

There total 4 articles about 2-(Perfluorododecyl)ethyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + 1H,1H,2H,2H-tridecafluoro-n-octanol (647-42-7) + 2-(perfluorodecyl)ethanol (865-86-1) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene (25291-17-2) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + C14F29CH=CH2 (104564-28-5) + C16F33CH=CH2 + 1H,1H,2H,2H-perfluorohexadecan-1-ol (60699-51-6) + C14F29CH2CH2OCOCH=CH2 (34362-49-7) + C16F33CH2CH2OCOCH=CH2 + C18F37CH2CH2OCOCH=CH2 (65104-64-5) + 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

1H,1H,2H,2H-perfluorohexadecan-1-ol (60699-51-6) + 1H,1H,2H,2H-perfluorooctadecan-1-ol (65104-67-8) + 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + acrylic acid (79-10-7) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + C14F29CH2CH2OCOCH=CH2 (34362-49-7) + C16F33CH2CH2OCOCH=CH2 + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

With hydroquinone; toluene-4-sulfonic acid; In toluene; for 4h; Product distribution / selectivity;

upstream raw materials:

1H,1H,2H,2H-perfluorohexadecan-1-ol

1H,1H,2H,2H-perfluorooctadecan-1-ol

2-(perfluorodecyl)ethanol

1H,1H,2H,2H-perfluorobutadecan-1-ol

Refernces

• 1、 -. "PROCESS FOR PRODUCING FLUORINATED ACRYLIC ESTER". Page/Page column 6-7; 8-9. . Retrieved 2008/06/13.