3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl acrylate

Base Information

• Chemical Name: 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl acrylate
• CAS No.: 17741-60-5
• Deprecated CAS: 137738-90-0,1040032-83-4,1040032-83-4
• Molecular Formula: C15H7 F21 O2
• Molecular Weight: 618.186
• Hs Code.: 2916129000
• European Community (EC) Number: 241-732-2
• UNII: 39G0Q51SIY
• DSSTox Substance ID: DTXSID9037743
• Nikkaji Number: J26.241B
• Wikidata: Q27256898
• Mol file: 17741-60-5.mol

Synonyms:10-2 fluorotelomer acrylate;10:2 fluorotelomer acrylate;10:2 FTAC;3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl prop-2-enoate;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl prop-2-enoate;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl prop-2-enoate;6-2 fluorotelomer acrylate;6:2 fluorotelomer acrylate;6:2 FTAC;8-2 fluorotelomer acrylate;8:2 fluorotelomer acrylate;8:2 FTAC;fluorotelomer acrylate;fluorotelomer acrylate polymers

Chemical Property of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl acrylate

Chemical Property:

• Melting Point: 48-53 ºC
• Boiling Point: 122 ºC (4 mmHg)
• Flash Point: >110 ºC
• PSA: 26.30000
• Density: 1.32
• LogP: 7.38570
• Storage Temp.: 2-8°C
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
• XLogP3: 8.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 23
• Rotatable Bond Count: 13
• Exact Mass: 618.0110709
• Heavy Atom Count: 38
• Complexity: 884

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-?(Perfluorodecyl)?ethylAcrylate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(=O)OCCC(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: 2-?(Perfluorodecyl)?ethyl Acrylate is used as a reagent in the preparation of repellent finishes on cotton.

Technology Process of 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl acrylate

There total 7 articles about 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl acrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H-perfluorodecene (21652-58-4) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

2-(perfluorodecyl)ethanol (865-86-1) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + acrylic acid (79-10-7) → 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

With hydroquinone; toluene-4-sulfonic acid; In toluene; for 4h; Product distribution / selectivity;

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + 1H,1H,2H,2H-tridecafluoro-n-octanol (647-42-7) + 2-(perfluorodecyl)ethanol (865-86-1) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene (25291-17-2) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

upstream raw materials:

2-(perfluorodecyl)ethanol

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol

acrylic acid

1H,1H,2H,2H-perfluorohexadecan-1-ol

Refernces

• 1、 -. "PROCESS FOR PRODUCING FLUORINATED ACRYLIC ESTER". Page/Page column 6-7; 8-9. . Retrieved 2008/06/13.