1h,1h,2h-Perfluoro-1-dodecene

Base Information

• Chemical Name: 1h,1h,2h-Perfluoro-1-dodecene
• CAS No.: 30389-25-4
• Molecular Formula: C12H3F21
• Molecular Weight: 546.122
• Hs Code.: 2903399090
• European Community (EC) Number: 250-173-3
• DSSTox Substance ID: DTXSID60184471
• Nikkaji Number: J28.316I
• Wikidata: Q72500482
• Mol file: 30389-25-4.mol

Synonyms:1h,1h,2h-Perfluoro-1-dodecene;30389-25-4;(Perfluorodecyl)ethylene;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene;EINECS 250-173-3;1H,1H,2H-Perfluorododec-1-ene;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecene;C12H3F21;(N-Perfluorodecyl)ethylene;SCHEMBL2118364;DTXSID60184471;MFCD00042346;AKOS025309993;C12-H3-F21;C12 Gamma-Omega Perfluoro Alpha-Alkene;1H,1H,2H-perfluoro-1-dodecene, 97%;CS-0318160;FT-0604970;A820352;1-Dodecene, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluoro-;1-Dodecene,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluoro-;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluoro-1-dodecene;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluoro-1-dodecene;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosakis(fluoranyl)dodec-1-ene

Chemical Property of 1h,1h,2h-Perfluoro-1-dodecene

Chemical Property:

• Vapor Pressure: 0.979mmHg at 25°C
• Refractive Index: 1.303
• Boiling Point: 184.9 °C at 760 mmHg
• Flash Point: 72.1 °C
• PSA: 0.00000
• Density: 1.622 g/cm³
• LogP: 7.45240
• XLogP3: 8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 9
• Exact Mass: 545.9899415
• Heavy Atom Count: 33
• Complexity: 737

Purity/Quality:

99% ^*data from raw suppliers

1H,1H,2H-Perfluoro-1-dodecene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: 1H,1H,2H-Perfluoro-1-dodecene is used in preparation method of coating for surface modification of photoresist.

Technology Process of 1h,1h,2h-Perfluoro-1-dodecene

There total 8 articles about 1h,1h,2h-Perfluoro-1-dodecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H-perfluorodecene (21652-58-4) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + 1H,1H,2H,2H-tridecafluoro-n-octanol (647-42-7) + 2-(perfluorodecyl)ethanol (865-86-1) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene (25291-17-2) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

Reference yield:

polytetrafluoroethylene (116-14-3,82785-14-6) + ethene (74-85-1) + Pentafluoroethyl iodide (354-64-3) + potassium acrylate (10192-85-5) → 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro-tetradecyl acrylate (34395-24-9) + 1H,1H,2H-perfluoro-1-tetradecene + C14F29CH=CH2 (104564-28-5) + C16F33CH=CH2 + 1H,1H,2H,2H-perfluorohexadecan-1-ol (60699-51-6) + C14F29CH2CH2OCOCH=CH2 (34362-49-7) + C16F33CH2CH2OCOCH=CH2 + C18F37CH2CH2OCOCH=CH2 (65104-64-5) + 2-(perfluorodecyl)ethanol (865-86-1) + 1H,1H,2H-perfluorodecene (21652-58-4) + 1H,1H,2H,2H-perfluorobutadecan-1-ol (39239-77-5) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-decanol (678-39-7) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) + 1H,1H,2H,2H-heptadecafluorodecyl acrylate (27905-45-9) + 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate (17527-29-6) + 1,1,2,2-Tetrahydroperfluorododecyl acrylate (17741-60-5)

Guidance literature:

polytetrafluoroethylene; Pentafluoroethyl iodide; copper catalyst; at 80 ℃; under 6000.6 Torr;

ethene; copper catalyst; at 100 ℃; for 3h; under 2250.23 Torr;

potassium acrylate; With 4-methoxy-phenol; hydroquinone; In tert-butyl alcohol; at 180 - 190 ℃; for 6h; Product distribution / selectivity;

upstream raw materials:

1-iodo-1H,1H,2H,2H-perfluorododecane

1-Iodo-perfluorodecane

1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane

2-(n-perfluorooctyl)ethyl iodide

Downstream raw materials:

1H,1H,2H,2H-perfluorododecyltriethoxysilane

(1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane

trichloro-(1H,1H,2H,2H-henicosafluorododecyl)silane

Refernces

• 1、 -. "PROCESS FOR PRODUCING FLUORINATED (METH)ACRYLIC ESTER". Page/Page column 8-9. . Retrieved 2010/11/25.