1H,1H,2H,2H-Perfluorododecyltrimethoxysilane

Base Information

• Chemical Name: 1H,1H,2H,2H-Perfluorododecyltrimethoxysilane
• CAS No.: 123445-18-1
• Molecular Formula: C₁₅H₁₃F₂₁O₃Si
• Molecular Weight: 668.318
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID40895553
• Nikkaji Number: J607.036A
• Wikidata: Q82871804
• Mol file: 123445-18-1.mol

Synonyms:1H,1H,2H,2H-Perfluorododecyltrimethoxysilane;123445-18-1;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl(trimethoxy)silane;Silane,(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluorododecyl)trimethoxy-;SCHEMBL1462442;DTXSID40895553;VQIWEYGMCDFBSW-UHFFFAOYSA-N;2-(Perfluorodecyl)ethyl(trimethoxy)silane;NS00110378;(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-Henicosafluorododecyl)(trimethoxy)silane

Chemical Property of 1H,1H,2H,2H-Perfluorododecyltrimethoxysilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 24
• Rotatable Bond Count: 14
• Exact Mass: 668.0298622
• Heavy Atom Count: 40
• Complexity: 871

Purity/Quality:

97% ^*data from raw suppliers

1H,1H,2H,2H-Perfluorododecyltrimethoxysilane 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CO[Si](CCC(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(OC)OC

Technology Process of 1H,1H,2H,2H-Perfluorododecyltrimethoxysilane

There total 3 articles about 1H,1H,2H,2H-Perfluorododecyltrimethoxysilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.9%

trimethoxysilane (2487-90-3) + 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) → (1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane (123445-18-1)

Guidance literature:

With chloroplatinic acid; In isopropyl alcohol; at 25 ℃; for 0.118333h;

Reference yield: 75.8%

sodium methylate (124-41-4) + trichloro-(1H,1H,2H,2H-henicosafluorododecyl)silane (102488-49-3) → (1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane (123445-18-1)

Guidance literature:

In methanol; 1,1,2-Trichloro-1,2,2-trifluoroethane; for 1h; Ambient temperature;

DOI:10.1246/bcsj.66.1754

Reference yield:

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) → (1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane (123445-18-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 98.6 percent / trichlorosilane, methanolic hydrogen hexachloroplatinate(IV) / 70 h / 100 °C

2: 75.8 percent / 1,1,2-trichloro-1,2,2-trifluoro-ethane; methanol / 1 h / Ambient temperature

With dihydrogen hexachloroplatinate; trichlorosilane; In methanol; 1,1,2-Trichloro-1,2,2-trifluoroethane;

DOI:10.1246/bcsj.66.1754

upstream raw materials:

sodium methylate

trichloro-(1H,1H,2H,2H-henicosafluorododecyl)silane

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene

trimethoxysilane

Refernces

• 1、 Yoshino, Norio,Yamamoto, Yasushi,Hamano, Katsumi,Kawase, Tokuzo. "Syntheses and Reactions of Metal Organics. XVIII. Syntheses of (1H,1H,2H,2H-Polyfluoroalkyl)trimethoxysilanes and Surface Modification of Glass Plate". . p. 1754 - 1758. Retrieved 2007/10/02.