1H,1H,2H,2H-Perfluorododecyltrichlorosilane

Base Information

• Chemical Name: 1H,1H,2H,2H-Perfluorododecyltrichlorosilane
• CAS No.: 102488-49-3
• Molecular Formula: C₁₂H₄Cl₃F₂₁Si
• Molecular Weight: 681.575
• Hs Code.: 2931900090
• European Community (EC) Number: 662-991-1
• DSSTox Substance ID: DTXSID40382352
• Nikkaji Number: J1.718.069J
• Wikidata: Q81985907
• Mol file: 102488-49-3.mol

Synonyms:1H,1H,2H,2H-Perfluorododecyltrichlorosilane;102488-49-3;trichloro(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl)silane;Silane, trichloro(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluorododecyl)-;SCHEMBL892529;DTXSID40382352;ZFUVZJADECZZMS-UHFFFAOYSA-N;MFCD07368770;AKOS015911226;AS-79983;2-(Henicosafluorodecyl)ethyltrichlorosilane;HENEICOSAFLUORODODECYLTRICHLOROSILANE;[2-(Perfluorodec-1-yl)ethyl]trichlorosilane;[2-(Perfluorodec-1-yl)ethyl]trichlorosilane 97%;1H,1H,2H,2H-Perfluorododecyltrichlorosilane, 97%;J-000698

Chemical Property of 1H,1H,2H,2H-Perfluorododecyltrichlorosilane

Chemical Property:

• Melting Point: 50-55°C
• Boiling Point: 264.7°Cat760mmHg
• Flash Point: 113.9°C
• PSA: 0.00000
• Density: 1.656g/cm³
• LogP: 9.31180
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 10
• Exact Mass: 679.881251
• Heavy Atom Count: 37
• Complexity: 826

Purity/Quality:

98%,99%, ^*data from raw suppliers

1H,1H,2H,2H-Perfluorododecyltrichlorosilane 97% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 14-34
• Safety Statements: 22-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C[Si](Cl)(Cl)Cl)C(C(C(C(C(C(C(C(C(C(F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)(F)F
• Uses: FTCS can be incorporated in polyvinylidiene fluoride(PVDF) with titanium oxide(TiO2) which can be used for membrane distillation for water treatment and anti-fouling based application.

Technology Process of 1H,1H,2H,2H-Perfluorododecyltrichlorosilane

There total 1 articles about 1H,1H,2H,2H-Perfluorododecyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.6%

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene (30389-25-4) → trichloro-(1H,1H,2H,2H-henicosafluorododecyl)silane (102488-49-3)

Guidance literature:

With dihydrogen hexachloroplatinate; trichlorosilane; at 100 ℃; for 70h;

DOI:10.1246/bcsj.66.1754

Reference yield: 75.8%

sodium methylate (124-41-4) + trichloro-(1H,1H,2H,2H-henicosafluorododecyl)silane (102488-49-3) → (1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane (123445-18-1)

Guidance literature:

In methanol; 1,1,2-Trichloro-1,2,2-trifluoroethane; for 1h; Ambient temperature;

DOI:10.1246/bcsj.66.1754

upstream raw materials:

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododec-1-ene

Downstream raw materials:

(1H,1H,2H,2H-henicosafluorododecyl)trimethoxysilane

Refernces

• 1、 Yoshino, Norio,Yamamoto, Yasushi,Hamano, Katsumi,Kawase, Tokuzo. "Syntheses and Reactions of Metal Organics. XVIII. Syntheses of (1H,1H,2H,2H-Polyfluoroalkyl)trimethoxysilanes and Surface Modification of Glass Plate". . p. 1754 - 1758. Retrieved 1993.