decalin-4a-ol

Base Information

• Chemical Name: decalin-4a-ol
• CAS No.: 3574-58-1
• Molecular Formula: C10H18 O
• Molecular Weight: 154.252
• Hs Code.: 2906199090
• Mol file: 3574-58-1.mol

Synonyms:4a(2H)-Naphthol,octahydro-, cis- (8CI); cis-9-Decalinol; cis-9-Decalol;cis-Bicyclo[4.4.0]decan-1-ol

Chemical Property of decalin-4a-ol

Chemical Property:

• Vapor Pressure: 0.00698mmHg at 25°C
• Boiling Point: 239.6°Cat760mmHg
• Flash Point: 98.2°C
• PSA: 20.23000
• Density: 1.027g/cm³
• LogP: 2.48170

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of decalin-4a-ol

There total 20 articles about decalin-4a-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

cis-decalin (493-01-6) → cis-9,10-decalinediol (28795-95-1) + cis-9-decalol (3574-58-1) + cis-1-decalone (32166-40-8) + cis-2-decalone (1579-21-1)

Guidance literature:

With methyltrifluoromethyldioxirane; In dichloromethane; at -22 ℃; for 0.0833333h; Yields of byproduct given;

DOI:10.1021/ja00199a039

Reference yield: 75.0%

6-bromocyclododecanone (87307-15-1) → cyclodecanone (1502-06-3) + trans-decal-9-ol (1654-87-1) + cis-9-decalol (3574-58-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 60 ℃; for 15h;

DOI:10.1021/jo00172a051

Reference yield: 20.0%

cis-decalin (493-01-6) → cis-9-decalol (3574-58-1) + (4ar,8ar)-octahydronaphthalene-4a,8a-diol (57289-63-1)

Guidance literature:

With 2,2,2-trifluoro-1-(4-fluorophenyl)ethanone; dihydrogen peroxide; acetic acid; In 1,2-dichloro-ethane; at 70 ℃; for 72h; chemoselective reaction;

DOI:10.1021/ol503410e

upstream raw materials:

pyridine N-oxide

cis-decalin

trans-Decalin

6-bromocyclododecanone

Downstream raw materials:

(4ar,8ar)-octahydronaphthalene-4a,8a-diol

2-butylcyclohexanone

formic acid

2-(4-bromo-butyl)-cyclohexanone

Refernces

• 1、 Mettry, Magi,Moehlig, Melissa Padilla,Gill, Adam D.,Hooley, Richard J.. "Alkane oxidation catalysed by a self-folded multi-iron complex". . p. 120 - 128. Retrieved 2016/11/09.
• 2、 Prat, Irene,Gomez, Laura,Canta, Merce,Ribas, Xavi,Costas, Miquel. "An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites". supporting information. p. 1908 - 1913. Retrieved 2013/03/14.