Nitrogen-15N2

Base Information

• Chemical Name: Nitrogen-15N2
• CAS No.: 29817-79-6
• Molecular Formula: N2
• Molecular Weight: 34.0318
• DSSTox Substance ID: DTXSID70436579
• Nikkaji Number: J96.484K
• Wikidata: Q82251868
• Mol file: 29817-79-6.mol

Synonyms:Nitrogen-15N2;29817-79-6;nitrogen-15N;[15N]-Nitrogen;Nitrogen, mol. (15N2);DTXSID70436579;CS-BX-00247;Nitrogen-15N2, 98 atom % 15N;AKOS015903209

Chemical Property of Nitrogen-15N2

Chemical Property:

• PSA: 47.58000
• Density: 0.875g/cm³
• LogP: 0.03016
• XLogP3: 0.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 30.00021780
• Heavy Atom Count: 2
• Complexity: 8

Purity/Quality:

99%, ^*data from raw suppliers

Nitrogen-15N2 98 atom % ^*data from reagent suppliers

Safty Information:

• Safety Statements: 38

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N#N
• Isomeric SMILES: [15N]#[15N]

Technology Process of Nitrogen-15N2

There total 36 articles about Nitrogen-15N2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(15)N2H5(1+) + cis-nitrous acid (7782-77-6) → nitrogen-15 (29817-79-6) + nitrous oxide (35305-17-0) + nitrogen (17787-11-0) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With perchloric acid; In neat (no solvent); byproducts: H2O; (15)N2H5(1+) reacted with excess of HNO2;

Reference yield:

nitrous acid (7782-77-6) + [15N2]-hydrazine (29817-79-6) → nitrogen-15 (29817-79-6) + nitrous oxide (35305-17-0) + nitrogen (17787-11-0) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With hydrogen cation; byproducts: H2O; products ratio: 2:1 for (15)N2:(15)NN and 2:1 for (15)NNO:N2O; monitored by mass-spectrometrically;

DOI:10.1039/c39810000299

Reference yield:

ammonia (7664-41-7) + 15N labeled nitric oxide (15917-77-8) → nitrogen-15 (29817-79-6) + nitrogen (17787-11-0) + (14,15)NO (20509-24-4) + nitrogen (7727-37-9) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In gas; react. of NH3 and NO in gaseous phase over Co(en)2(NO2)3, ion exchangedinto Na-Y-zeolite; further products; not isolated, detected by quadrupole MAS; Kinetics;

DOI:10.1021/j100225a029

upstream raw materials:

trans-sodium-vanadium(-I)(⁽¹⁵⁾N₂)2(bis(dimethylphosphino)ethane)2

water

ammonia

¹⁵N labeled nitric oxide

Downstream raw materials:

ammonia

nitrous oxide

nitrogen

dinitrogen monoxide

Refernces

• 1、 Smirnov,Zemlyanov,Vovk. "Mechanism of the reaction NO + H2 on the Pt(100)-hex surface under conditions of the spatially nonuniform distribution of reacting species". . p. 853 - 863. Retrieved 2007.
• 2、 Zhao, Guoliang,Wang, Xin,Xu, Chen. "MXene-Derived Nanocomposites as Earth-Abundant Efficient Electrocatalyst for Nitrogen Reduction Reaction under Ambient Conditions". supporting information. p. 16672 - 16678. Retrieved 2020/11/13.
• 3、 MacLeod, K. Cory,Vinyard, David J.,Holland, Patrick L.. "A multi-iron system capable of rapid N2 formation and N 2 cleavage". . p. 10226 - 10229. Retrieved 2014/08/05.