Ruthenium(2+) azanide--ammonia (1/2/4)

Base Information

• Chemical Name: Ruthenium(2+) azanide--ammonia (1/2/4)
• CAS No.: 19052-44-9
• Molecular Formula: H18N6 Ru
• Molecular Weight: 274.159
• DSSTox Substance ID: DTXSID40940618
• Mol file: 19052-44-9.mol

Synonyms:DTXSID40940618;Ruthenium(2+) azanide--ammonia (1/2/4)

Chemical Property of Ruthenium(2+) azanide--ammonia (1/2/4)

Chemical Property:

• Vapor Pressure: 5990mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 65.00000
• Density: g/cm³
• LogP: 2.72980
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 202.047985
• Heavy Atom Count: 7
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

HEXAMMINERUTHENIUM(2 ) ION 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N.N.N.N.[NH2-].[NH2-].[Ru+2]

Technology Process of Ruthenium(2+) azanide--ammonia (1/2/4)

There total 26 articles about Ruthenium(2+) azanide--ammonia (1/2/4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

ammonia (7664-41-7) + ruthenium(III)chloride (10049-08-8,63767-78-2) → hexaammineruthenium(II) chloride (19052-44-9,15305-72-3)

Guidance literature:

With Zn; NH₄Cl; In water; prepn. from RuCl3 and aq. NH3 and Zn metal in the presence of NH4Cl according to F. M. Lever and A.R. Powell, J. Chem.Soc. A 9, 1477 (1969);

DOI:10.1134/S0036023607010123

Reference yield:

hexammine ruthenium(III) chloride (14282-91-8) → hexaammineruthenium(II) chloride (19052-44-9,15305-72-3)

Guidance literature:

With mercury; zinc; In water; Ru-complex dissolved in distd., deionized water, soln. deoxygenated with Ar gas, Zn/Hg added, 15 min.;

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) + ammonium chloride + ammonia (7664-41-7) → hexaammineruthenium(II) chloride (19052-44-9,15305-72-3)

Guidance literature:

With zinc; In hydrogenchloride; ammonia; boiling 15 g RuCl3*3H2O in 50 ml concd. HCl and stirring for 1 h; addn. of a stirred soln. of 5 g NH4Cl in 150 ml aq. NH3 (density 0.880) drop by drop; addn. of 7.5 g Zn dust in small portions (0.5 g); formation of a yellow soln. on boiling;; addn. of 40 NH4Cl to the hot filtrate, cooling, pptn.; washing with 15 ml 20 % NH4Cl in aq. NH3 and acetone; drying in vac. over P2O5;;

upstream raw materials:

ruthenium(III) chloride trihydrate

hydrazine hydrate

ammonia

ruthenium(III)chloride

Downstream raw materials:

hexaammineruthenium(III)

dihydrogen peroxide

hexaammineruthenium(II) chloride

hexammine ruthenium(III) chloride

Refernces

• 1、 Sakamoto, Tetsuo,Ohsako, Tatsuya,Matsuo, Taku,Mulac, William A.,Meisel, Dan. "PULSE RADIOLYSIS STUDIES OF ELECTRON TRANSFER BETWEEN POLYMER AND ZWITTERIONIC VIOLOGEN RADICALS". . p. 1893 - 1896. Retrieved 1984.
• 2、 Rodríguez-López, Joaquín,Alpuche-Avilés, Mario A.,Bard, Allen J.. "Interrogation of surfaces for the quantification of adsorbed species on electrodes: Oxygen on gold and platinum in neutral media". . p. 16985 - 16995. Retrieved 2008.
• 3、 Peter, Laurence M.,Ushiroda, Shin. "Microwave reflectance studies of photoelectrochemical kinetics at semiconductor electrodes. 3. Photoelectrochemical reduction of Ru(NH3)63+ at p-Si". . p. 2660 - 2665. Retrieved 2004.
• 4、 Vijaikanth, Vijendran,Li, Guangchun,Swaddle, Thomas W.. "Kinetics of reduction of aqueous hexaammineruthenium(III) ion at Pt and Au microelectrodes: Electrolyte, temperature, and pressure effects". . p. 2757 - 2768. Retrieved 2013.
• 5、 Baddam, Saritha,Bowler, Bruce E.. "Tuning the rate and pH accessibility of a conformational electron transfer gate". . p. 6338 - 6346. Retrieved 2008/10/09.