Technology Process of (E)-benzyl5-(4-octylstyryl)-2,2-diMethyl-1,3- dioxan-5-ylcarbaMate
There total 7 articles about (E)-benzyl5-(4-octylstyryl)-2,2-diMethyl-1,3- dioxan-5-ylcarbaMate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium carbonate;
In
tetrahydrofuran; N,N-dimethyl-formamide;
for 6h;
Product distribution / selectivity;
Reflux;
- Guidance literature:
-
Multi-step reaction with 2 steps
1: toluene / 6 h / Reflux; Inert atmosphere
2: potassium carbonate / tetrahydrofuran; N,N-dimethyl-formamide / 20 h / Reflux
With
potassium carbonate;
In
tetrahydrofuran; N,N-dimethyl-formamide; toluene;
2: Wittig reaction;
DOI:10.1007/s00706-011-0582-7
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1-methyl-pyrrolidin-2-one; iron(III)-acetylacetonate / tetrahydrofuran / 0.75 h / -5 °C / Inert atmosphere
2: potassium borohydride; lithium chloride / tetrahydrofuran / 8 h / Reflux
3: phosphorus tribromide / dichloromethane / 4.3 h / -10 - 20 °C
4: toluene / 6 h / Reflux; Inert atmosphere
5: potassium carbonate / tetrahydrofuran; N,N-dimethyl-formamide / 20 h / Reflux
With
1-methyl-pyrrolidin-2-one; potassium borohydride; iron(III)-acetylacetonate; phosphorus tribromide; potassium carbonate; lithium chloride;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; toluene;
5: Wittig reaction;
DOI:10.1007/s00706-011-0582-7
