2-Bromo-3-nitronaphthalene

Base Information

• Chemical Name: 2-Bromo-3-nitronaphthalene
• CAS No.: 67116-33-0
• Molecular Formula: C10H6BrNO2
• Molecular Weight: 252.067
• Hs Code.: 2904909090
• DSSTox Substance ID: DTXSID40474741
• Wikidata: Q82304858
• Mol file: 67116-33-0.mol

Synonyms:2-bromo-3-nitronaphthalene;67116-33-0;Naphthalene,2-bromo-3-nitro-;SCHEMBL11205014;DTXSID40474741;AKOS015835936;BB 0260444;FT-0677519;A854450

Chemical Property of 2-Bromo-3-nitronaphthalene

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 82-83 °C
• Refractive Index: 1.696
• Boiling Point: 338.13 °C at 760 mmHg
• Flash Point: 158.295 °C
• PSA: 45.82000
• Density: 1.663 g/cm³
• LogP: 4.03370
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 250.95819
• Heavy Atom Count: 14
• Complexity: 229

Purity/Quality:

98%min ^*data from raw suppliers

2-Bromo-3-nitronaphthalene 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C=C(C(=CC2=C1)[N+](=O)[O-])Br

Technology Process of 2-Bromo-3-nitronaphthalene

There total 11 articles about 2-Bromo-3-nitronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

10-bromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-11-nitro-1,4-5,8-dimethanotriphenylene (84605-00-5) → 2-bromo-3-nitronaphthalene (67116-33-0)

Guidance literature:

at 220 ℃; under 0.05 - 0.1 Torr;

Reference yield:

2-bromo-3-nitro-[1]naphthylamine (90766-99-7) → 2-bromo-3-nitronaphthalene (67116-33-0)

Guidance literature:

With sulfuric acid; acetic acid; Diazotization_.Behandlung der Diazoniumsalz-Loesung mit Cu₂O in Methanol oder mit siedendem Aethanol;

DOI:10.1016/S1067-2516(02)80038-2 DOI:10.1039/jr9360001151

Reference yield:

3-bromo-2-nitro-[1]naphthylamine (856210-98-5) → 2-bromo-3-nitronaphthalene (67116-33-0)

Guidance literature:

With sulfuric acid; acetic acid; Diazotization_.Behandlung der Diazoniumsalz-Loesung mit Cu₂O in Methanol oder mit siedendem Aethanol;

DOI:10.1016/S1067-2516(02)80038-2 DOI:10.1039/jr9360001151

upstream raw materials:

2-bromo-3-nitro-[1]naphthylamine

3-bromonaphthalen-2-amine

6-Brom-7-nitro-tetralin

3-bromo-2-nitro-[1]naphthylamine

Downstream raw materials:

3-bromonaphthalen-2-amine

2-iodo-3-nitronaphthalene

3-phenyl-2-nitronapthalene

2,3-benzocarbazole

Refernces

• 1、 Kelly, T. Ross,Kim, Min H.. "Relative binding affinity of carboxylate and its isosteres: Nitro, phosphate, phosphonate, sulfonate, and δ-lactone". . p. 7072 - 7080. Retrieved 2007/10/02.