carbomethoxymethanethiolate

Base Information

• Chemical Name: carbomethoxymethanethiolate
• CAS No.: 64743-45-9
• Molecular Formula: C₃H₅O₂S
• Molecular Weight: 105.138
• Mol file: 64743-45-9.mol

Synonyms:carbomethoxymethanethiolate

Chemical Property of carbomethoxymethanethiolate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of carbomethoxymethanethiolate

There total 16 articles about carbomethoxymethanethiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C11H12NO4S(1-) → (2-nitroethenyl)benzene (102-96-5) + methyl {[alpha-(nitromethyl)benzyl]thio}acetate (76665-83-3,91134-32-6) + carbomethoxymethanethiolate (64743-45-9)

Guidance literature:

With acetic acid; In water; acetonitrile; Rate constant; Equilibrium constant; acetate buffer; pH-jump experiments;

DOI:10.1021/jo00034a032

Reference yield:

C17H16NO4S(1-) → ((Z)-(1-nitroethene-1,2-diyl)dibenzene) (15341-31-8) + carbomethoxymethanethiolate (64743-45-9)

Guidance literature:

With potassium chloride; In water; dimethyl sulfoxide; at 20 ℃; Rate constant; Equilibrium constant;

Reference yield:

C18H18NO5S(1-) (122801-33-6) → (E)-β-Methoxy-α-nitrostilbene (96746-56-4) + carbomethoxymethanethiolate (64743-45-9)

Guidance literature:

With potassium chloride; In water; dimethyl sulfoxide; at 20 ℃; Rate constant; Equilibrium constant;

upstream raw materials:

C₁₈H₁₈NO₅S^(1-)

Downstream raw materials:

N,N-dimethyl-3-nitroaniline

[(methoxymethyl)thio]acetic acid methyl ester

(CO)5CrC(C₆H₅)SCH₂C(O)OCH₃

(CO)5WC(C₆H₅)SCH₂C(O)OCH₃

Refernces

• 1、 Bernasconi, Claude F.,Ketner, Rodney J.,Chen, Xin,Rappoport, Zvi. "Detection and kinetic characterization of SNV intermediates. Reactions of thiomethoxybenzylidene Meldrum's acid with thiolate ions, alkoxide ions, OH-, and water in aqueous DMSO". . p. 584 - 594. Retrieved 2007/10/03.
• 2、 Bernasconi, Claude F.,Schuck, David F.. "Kinetics of Reversible Thiolate Ion Addition to Substituted β-Nitrostyrenes in Water. Radicaloid Transition State or Principle of Nonperfect Synchronization?". . p. 2365 - 2373. Retrieved 2007/10/02.