o-methoxybenzenesulfenyl chloride

Base Information

• Chemical Name: o-methoxybenzenesulfenyl chloride
• CAS No.: 71556-63-3
• Molecular Formula: C₇H₇ClOS
• Molecular Weight: 174.651
• Mol file: 71556-63-3.mol

Synonyms:o-methoxybenzenesulfenyl chloride

Chemical Property of o-methoxybenzenesulfenyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of o-methoxybenzenesulfenyl chloride

There total 3 articles about o-methoxybenzenesulfenyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methoxybenzenethiol (7217-59-6) → o-methoxybenzenesulfenyl chloride (71556-63-3)

Guidance literature:

With tetrachloromethane; chlorine;

Reference yield:

bis(2-methoxyphenyl)disulfide (13920-94-0) → o-methoxybenzenesulfenyl chloride (71556-63-3)

Guidance literature:

With sulfuryl dichloride; triethylamine; In tetrachloromethane; at 20 ℃; for 0.5h;

DOI:10.1021/jm0102304

Reference yield:

N-chloro-succinimide (128-09-6) + 2-Methoxybenzenethiol (7217-59-6) → o-methoxybenzenesulfenyl chloride (71556-63-3)

Guidance literature:

In dichloromethane; at -40 - 0 ℃;

DOI:10.1021/ol015547c

upstream raw materials:

2-Methoxybenzenethiol

bis(2-methoxyphenyl)disulfide

N-chloro-succinimide

Downstream raw materials:

1-(trans-2-chloro-vinylmercapto)-2-methoxy-benzene

(3-chloro-4-methylsulfanyl-phenyl)-oxo-acetic acid methyl ester

3-[2-(2-methoxy-phenylsulfanyl)-1H-indol-3-yl]-propionic acid methyl ester

3-chloro-4-methylthio-acetophenone

Refernces

• 1、 Surineni, Naresh,Buragohain, Pori,Saikia, Bishwajit,Barua, Nabin C.,Baruah, Rajani K.. "A metal free chlorothiolation strategy for synthesis of vinyl sulfides from internal alkynoates". supporting information. p. 6965 - 6969. Retrieved 2015/11/27.
• 2、 Ercegovic, Teddy,Meijer, Andreas,Magnusson, Goeran,Ellervik, Ulf. "Iodine monochloride/silver trifluoromethanesulfonate (ICI/AgOTf) as a convenient promoter system for O-glycoside synthesis". . p. 913 - 915. Retrieved 2007/10/03.