Syn-oranti-octadecaborane

Base Information Edit

Chemical Name:Syn-oranti-octadecaborane
CAS No.:21107-56-2
Molecular Formula:B18H22
Molecular Weight:216.773
Hs Code.:
Mol file:21107-56-2.mol

Synonyms:ClusterBoron;anti-Octadecaborane(22);

Suppliers and Price of Syn-oranti-octadecaborane

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 13 raw suppliers

Chemical Property of Syn-oranti-octadecaborane Edit

Chemical Property:

PSA：0.00000
LogP:-14.35000

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Use Description Syn-oranti-octadecaborane is a chemical compound with applications in several fields. In the field of materials science and solid-state physics, it serves as a unique boron cluster compound, offering the potential for the development of novel materials with specialized properties. Researchers may explore its use in the synthesis of boron-rich materials for their distinctive electronic, magnetic, and structural properties. Additionally, in nuclear chemistry and radiation shielding, boron-containing compounds like syn-oranti-octadecaborane are studied for their neutron capture capabilities, potentially playing a role in radiation protection and boron neutron capture therapy (BNCT) for cancer treatment. Furthermore, in the realm of boron chemistry research, it is utilized as a reference compound and a starting material for the synthesis of other boron cluster compounds, contributing to the advancement of boron chemistry and its various applications. Its versatility underscores its significance in materials science, radiation shielding, and boron chemistry research, where it plays a crucial role in the development of new materials, radiation protection, and scientific investigation.

Technology Process of Syn-oranti-octadecaborane

There total 6 articles about Syn-oranti-octadecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.6%

: (CH₃)4N[nido-B₉H₁₂]

: 17702-41-9
nido-decaborane

: 21107-56-2
nido-decaborano⁽¹⁴⁾{6`,7`:5,6}nido-decaborane⁽¹⁴⁾

Guidance literature:: In toluene; Sonication; a flash charged with B compd. and toluene under Ar, sonicated, I2 and toluene added, stirred at room temp. for ca. 40 min; filtered, evapd., pumped overnight at room temp.;
DOI:10.1021/ic051712z

Reference yield: 68.0%

: dodecahydrononaborane^(1-) tetramethylammonium salt

: 21107-56-2
nido-decaborano⁽¹⁴⁾{6`,7`:5,6}nido-decaborane⁽¹⁴⁾

Guidance literature:: With mercury dibromide; In dichloromethane; byproducts: Hg, H2; HgBr2 was added with stirring under N2 atmosphere to a soln. of Me4NB9H12 in freshly distilled CH2Cl2, mixt. was stirred at room temp. overnight; filtered, filtrate evapd., residue was extd. with toluene, ext. filtered, evapd.; identified by comparison of (11)B NMR spectrum with that reported earlier;
DOI:10.1021/ja00335a079

Reference yield: 36.0%

: [N(CH₃)4][nido-B₉H₁₂]

: mercury dibromide

: 21107-56-2
nido-decaborano⁽¹⁴⁾{6`,7`:5,6}nido-decaborane⁽¹⁴⁾

: [N(CH₃)4][arachno-B₉H₁₂-4,8-Br₂]

Guidance literature:: In dichloromethane; byproducts: Hg; under dry N2 using Schlenk techniques; CH2Cl2 condensed into flask, contg. (NMe4)(nido-B9H12), HgBr2; mixt. warmed to room temp. with stirring; after 1 h mixt. filtered; solvent evapd. to dryness (vac.); residue extd. (toluene); filtered; isolated (NMe4)(B9H12Br2); toluene removed from filtrate; isolated anti-B18H22;
DOI:10.1021/ja025700d