CID 12622056

Base Information

• Chemical Name: CID 12622056
• CAS No.: 20621-02-7
• Molecular Formula: N2O
• Molecular Weight: 45.9994
• European Community (EC) Number: 687-863-2
• DSSTox Substance ID: DTXSID10504645
• Wikidata: Q82359286
• Mol file: 20621-02-7.mol

Synonyms:20621-02-7;CID 12622056;DTXSID10504645;AKOS015913588;Oxo(~15~N_2_)-1lambda~5~-diazyne;Nitrous oxide-15N2, 98 atom % 15N

Chemical Property of CID 12622056

Chemical Property:

• Melting Point: −91 °C(lit.)
• Boiling Point: −88 °C(lit.)
• PSA: 54.46000
• LogP: 0.06366
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 45.99513242
• Heavy Atom Count: 3
• Complexity: 25.8

Purity/Quality:

99% ^*data from raw suppliers

NITROUS OXIDE-15N2 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: O,Xn
• Statements: 8-20/21/22-40
• Safety Statements: 36/37/39-38-45

MSDS Files:

Useful:

• Canonical SMILES: [N-]=[N+]=O
• Isomeric SMILES: [15N-]=[15N+]=O

Technology Process of CID 12622056

There total 14 articles about CID 12622056 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium (15)N-nitrite (68378-96-1) + hydroxylamine hydrochloride (5470-11-1) → (15)N-nitrous oxide (20621-02-7) + nitrous oxide (35305-17-0) + (14,15)NO (20509-24-4) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With phosphate buffer; In water; soln. of Na(15)NO2 in H2O and mixt. of NH2OH*HCl with phosphate buffer (pH 7-9) were degassed on the vac. line by successive freeze-pump-thaw cycles, mixed, the reaction was initiated by rotation of the vessel, after 48 h aq. phase was frozen at 194K; collected at 77K;

Reference yield:

(2,3,7,8,12,13,17,18-octaethylporphyrinato)Fe(II)((15)NO) + nitrogen(II) oxide (10102-43-9) → (15)N-nitrous oxide (20621-02-7) + nitrous oxide (35305-17-0) + (14,15)NO (20509-24-4) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With potassium trimethylsilonate; [2.2.2]cryptande; In tetrahydrofuran; at 0 - 20 ℃; for 3h; Overall yield = 85 %Chromat.; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.7b13681

Reference yield:

C22H28N3(15)NNiO3 → (15)N-nitrous oxide (20621-02-7) + nitrous oxide (35305-17-0) + (14,15)NO (20509-24-4) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With 2Ni⁽²⁺⁾*2C₆H₁₂BO₃^(1-)*C₄H₄N₂*2NO^(1-); In dichloromethane-d2; at -42 ℃; for 0.0833333h; Irradiation;

DOI:10.1039/d1sc02846d

upstream raw materials:

sodium ⁽¹⁵⁾N-nitrite

hydroxylamine hydrochloride

nitric acid

deuterium

Downstream raw materials:

nitrogen-15

carbon dioxide

Refernces

• 1、 Abucayon, Erwin G.,Khade, Rahul L.,Powell, Douglas R.,Zhang, Yong,Richter-Addo, George B.. "Lewis Acid Activation of the Ferrous Heme-NO Fragment toward the N-N Coupling Reaction with NO to Generate N2O". supporting information. p. 4204 - 4207. Retrieved 2018/04/05.
• 2、 Kondratenko, Evgenii V.,Kondratenko, Vita A.,Richter, Manfred,Fricke, Rolf. "Influence of O2 and H2 on NO reduction by NH 3 over Ag/Al2O3: A transient isotopic approach". . p. 23 - 33. Retrieved 2008/10/09.