N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate

Base Information

• Chemical Name: N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate
• CAS No.: 851539-79-2
• Molecular Formula: C₃₂H₁₂BF₂₄*C₃₈H₃₀F₆N₃Pd
• Molecular Weight: 1612.31
• Mol file: 851539-79-2.mol

Synonyms:

Chemical Property of N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate

There total 1 articles about N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride (185406-04-6) + 3,5-bis(trifluoromethyl)benzonitrile (27126-93-8) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate (851539-79-2)

Guidance literature:

In dichloromethane; byproducts: NaCl; under Ar; CH2Cl2 added to Na borate and Pd complex at -78°C, 3,5-(CF3)2C6H3CN added, allowed to warm to room temp., stirred overnight; soln. filtered, filtrate evapd. under vac., pentane added to oily residue, stirred for 1.5 h, ppt. filtered off and dried under vac. for 3 h; elem. anal.;

DOI:10.1021/om040077m

Reference yield: 23.0%

vinyl acetate (108-05-4,9003-20-7) + N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)[(3,5-trifluoromethyl phenyl)cyanide] tetra(3,5-trifluoromethyl phenyl)borate (851539-79-2) → N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)(κ2-CH(OAc)Et) tetra(3,5-trifluoromethyl ph (851539-80-5)

Guidance literature:

In dichloromethane; (Ar), Pd complex in dry box cooled to 0°C, slowly treated with dry CH2Cl2 and vinyl acetate , stirred for 2 h, warmed to 20°C; chromy.(SiO2 - Et2O), crystd.(CH2Cl2-pentane) at -30°C, elem. anal., NMR; Kinetics;

DOI:10.1021/ja045969s

upstream raw materials:

N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II) methyl chloride

3,5-bis(trifluoromethyl)benzonitrile

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

Downstream raw materials:

N,N'-1,2-acenaphthylenediylidene bis(2,6-dimethyl aniline) palladium(II)(methyl)(κ2-CH(OAc)Et) tetra(3,5-trifluoromethyl ph

Refernces