1280126-09-1

Basic information

• Product Name: N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate
• Synonyms: N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate
• CAS NO: 1280126-09-1
• Molecular Weight: 347.237
• Mol File: 1280126-09-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate(1280126-09-1)
• EPA Substance Registry System: N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium hexafluorophosphate(1280126-09-1)

Safety Data

• Hazardous Substances Data: 1280126-09-1(Hazardous Substances Data)

Upstream product

• 118268-17-0 α-fluoromethyl-N-methyl-phenylsulphoximine 
• 65325-68-0 1-(monofluoromethyl sulfinyl)benzene 
• 60839-94-3 2-fluoro-methylthiobenzene 
• 100-68-5 methyl-phenyl-thioether 
• 7205-91-6 phenylthiomethyl chloride 
• 1280126-07-9 N,N-(dimethylamino)-S-phenyl-S-monofluoromethyloxosulfonium trifluoromethanesulfonate 
• 1280126-02-4 (fluoromethyl)(imino)(phenyl)-λ⁶-sulfanone 

Downstream Products

• 1280126-64-8 (2-(fluoromethoxy)-1H-indol-3-yl)(phenyl)methanone 
• 1280126-88-6 (4-(fluoromethoxy)phenyl)methanol 
• 1280126-86-4 1-butyl-4-(fluoromethoxy)benzene 
• 1280126-41-1 benzyl 3-(fluoromethoxy)-1H-indene-2-carboxylate 
• 114435-86-8 fluoromethyl 4-methylbenzenesulfonate 
• 1280126-82-0 fluoromethyl 2-phenylbutanoate 
• 1280126-76-2 fluoromethyl 3-nitrobenzoate 
• 1280126-51-3 benzyl 3-(fluoromethoxy)-2-(4-fluorophenyl)-3-phenylacrylate 
• 1280126-83-1 fluoromethyl 4-hydroxybenzoate 
• 1280126-81-9 fluoromethyl 2-(4-fluorophenyl)acetate 
• 1280126-55-7 dibenzyl 2-(fluoromethoxy)-1H-indole-1,3-dicarboxylate 

Relevant articles and documents

Inherent oxygen preference in enolate monofluoromethylation and a synthetic entry to monofluoromethyl ethers

Expect the unexpected: The self-stable salts 1, X=OTf, PF6, x=2, y=1, developed for electrophilic monofluoromethylation showed inherent selectivity for the O-alkylation of enolates, thus providing access to monofluoromethyl ethers, which are difficult to obtain by the direct electrophilic fluoromethylation of alcohols. Salt 1, X=BF4, x=0, y=3, in contrast leads to C-alkylated products.