183184-05-6

Basic information

• Product Name: (4R,5R)-4-methyl-5-phenyl-[1,3,2]dioxathiolane 2-oxide
• Synonyms: (4R,5R)-4-methyl-5-phenyl-[1,3,2]dioxathiolane 2-oxide
• CAS NO: 183184-05-6
• Molecular Weight: 198.243
• Mol File: 183184-05-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (4R,5R)-4-methyl-5-phenyl-[1,3,2]dioxathiolane 2-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,5R)-4-methyl-5-phenyl-[1,3,2]dioxathiolane 2-oxide(183184-05-6)
• EPA Substance Registry System: (4R,5R)-4-methyl-5-phenyl-[1,3,2]dioxathiolane 2-oxide(183184-05-6)

Safety Data

• Hazardous Substances Data: 183184-05-6(Hazardous Substances Data)

Upstream product

• 40421-51-0 (1R,2R)-1-phenylpropane-1,2-diol 

Downstream Products

• 204582-16-1 (4R,5R)-4-methyl-5-phenyl-1,3-dioxolan-2-one 
• 93-55-0 1-phenyl-propan-1-one 
• 160332-17-2 (1R,2R)-1-chloro-1-phenyl-2-propanol 

Relevant articles and documents

Nucleophilic ring opening of cyclic 1,2-sulfites with nitrogen nucleophiles. A route to enantiopure benzylic amino alcohols

The reaction between cyclic 1,2-sulfites and two imide and two sulfonamide nucleophiles has been investigated in order to develop a procedure for the enantioselective preparation of N-protected vicinal amino alcohols. The results show that both imide and sulfonamide anions react with cyclic sulfites, yielding the desired products. In some cases the regioselectivities are low, and for the sulfonamides products originating from nucleophilic addition to the sulfite sulfur are observed. Acta Chemica Scandinavica 1998.