25016-01-7 Usage
Description
5-Bromo-2-anisaldehyde, also known as 5-Bromo-2-methoxybenzaldehyde, is a light yellow crystalline powder with distinct spectral properties. It is an organic compound derived from anisaldehyde, featuring a bromine atom at the 5th position and a methoxy group at the 2nd position on the benzene ring. 5-Bromo-2-anisaldehyde is known for its unique chemical and physical properties, making it a versatile molecule for various applications across different industries.
Uses
Used in Chemical Synthesis:
5-Bromo-2-anisaldehyde is used as a key intermediate in the synthesis of various organic compounds, particularly those with potential applications in pharmaceuticals, agrochemicals, and materials science. Its unique structure allows for further functionalization and modification, making it a valuable building block in the development of new molecules with specific properties and functions.
Used in Pharmaceutical Industry:
5-Bromo-2-anisaldehyde is used as a starting material for the development of new drugs and pharmaceutical agents. Its chemical properties enable the creation of molecules with potential therapeutic applications, such as anti-inflammatory, analgesic, or anti-cancer agents. The compound's versatility in chemical reactions allows for the design and synthesis of novel drug candidates with improved efficacy and reduced side effects.
Used in Agrochemical Industry:
In the agrochemical industry, 5-Bromo-2-anisaldehyde is used as a precursor for the synthesis of bioactive compounds with potential applications as pesticides, herbicides, or insecticides. Its unique structure can be exploited to create molecules with enhanced biological activity and selectivity, leading to more effective and environmentally friendly agrochemical products.
Used in Materials Science:
5-Bromo-2-anisaldehyde is used as a component in the development of advanced materials with specific properties, such as optical, electronic, or magnetic functionalities. Its incorporation into polymers, coatings, or other materials can lead to the creation of novel materials with improved performance characteristics, such as enhanced stability, durability, or responsiveness to external stimuli.
Used in Research and Development:
5-Bromo-2-anisaldehyde is used as a research tool in academic and industrial laboratories for the study of various chemical and physical phenomena. Its unique properties make it an interesting subject for investigations into reaction mechanisms, molecular interactions, and the development of new synthetic methods or techniques.
Check Digit Verification of cas no
The CAS Registry Mumber 25016-01-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,5,0,1 and 6 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 25016-01:
(7*2)+(6*5)+(5*0)+(4*1)+(3*6)+(2*0)+(1*1)=67
67 % 10 = 7
So 25016-01-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H7BrO2/c1-11-8-3-2-7(9)4-6(8)5-10/h2-5H,1H3
25016-01-7Relevant articles and documents
Electricity Driven 1,3-Oxohydroxylation of Donor-Acceptor Cyclopropanes: a Mild and Straightforward Access to β-Hydroxy Ketones
Banerjee, Prabal,Maajid Taily, Irshad,Saha, Debarshi
supporting information, p. 5053 - 5057 (2021/09/30)
An unprecedented external oxidant-free electrochemical protocol for 1, 3-oxohydroxylation of donor-acceptor cyclopropane is disclosed. The strategy encompasses the activation of the labile π-electron cloud of the aryl ring to cleave the strained Csp3?Csp3 bond of cyclopropane to afford the β-hydroxy ketones via insertion of molecular oxygen. More significantly, based on the detailed mechanistic investigations and cyclic voltammetry experiments, a plausible mechanism is proposed.
V2O5@TiO2 Catalyzed Green and Selective Oxidation of Alcohols, Alkylbenzenes and Styrenes to Carbonyls
Upadhyay, Rahul,Kumar, Shashi,Maurya, Sushil K.
, p. 3594 - 3600 (2021/07/02)
The versatile application of different functional groups such as alcohols (1° and 2°), alkyl arenes, and (aryl)olefins to construct carbon-oxygen bond via oxidation is an area of intense research. Here, we report a reusable heterogeneous V2O5@TiO2 catalyzed selective oxidation of various functionalities utilizing different mild and eco-compatible oxidants under greener reaction conditions. The method was successfully applied for the alcohol oxidation, oxidative scission of styrenes, and benzylic C?H oxidation to their corresponding aldehydes and ketones. The utilization of mild and eco-friendly oxidizing reagents such as K2S2O8, H2O2 (30 % aq.), TBHP (70 % aq.), broad substrate scope, gram-scale synthesis, and catalyst recyclability are notable features of the developed protocol.
Monodentate Transient Directing Group Enabled Pd-Catalyzed Ortho-C-H Methoxylation and Chlorination of Benzaldehydes
Li, Feng,Zhou, Yirong,Yang, Heng,Wang, Ziqi,Yu, Qinqin,Zhang, Fang-Lin
supporting information, p. 3692 - 3695 (2019/05/24)
We report Pd-catalyzed ortho-C-H methoxylation and chlorination of benzaldehydes by employing monodentate transient directing groups (TDGs) as an alternative strategy to bidentate TDGs. More importantly, a single crystal of benzaldehyde imine ortho-cyclopalladium intermediate was successfully obtained, and its structure was unambiguously determined by X-ray diffraction, which clearly showed that it was a binuclear palladium species bridged by a pyridone ligand. The utility of this approach was further demonstrated through the synthesis of key intermediates of natural products and drugs.
