31641-78-8

Basic information

• Product Name: ethyl 2-diethoxyphosphoryl-2-phenylacetate
• Synonyms: ethyl 2-diethoxyphosphoryl-2-phenylacetate
• CAS NO: 31641-78-8
• Molecular Weight: 300.292
• Mol File: 31641-78-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: ethyl 2-diethoxyphosphoryl-2-phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-diethoxyphosphoryl-2-phenylacetate(31641-78-8)
• EPA Substance Registry System: ethyl 2-diethoxyphosphoryl-2-phenylacetate(31641-78-8)

Safety Data

• Hazardous Substances Data: 31641-78-8(Hazardous Substances Data)

Upstream product

• 2882-19-1 ethyl 2-phenyl-2-bromoacetate 
• 589-57-1 diethyl phosphorylchloridite 
• 101-97-3 Ethyl 2-phenylethanoate 
• 4870-65-9 2-bromophenylacetic acid 
• 774-40-3 hydroxy-phenyl-acetic acid ethyl ester 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 10606-73-2 ethyl 2-chloro-2-phenylacetate 
• 122-52-1 triethyl phosphite 
• 22065-57-2 ethyl 2-phenyldiazoacetate 
• 762-04-9 phosphonic acid diethyl ester 
• 591-50-4 iodobenzene 

Downstream Products

• 78427-49-3 (E)-2-phenyl-3-( pyridin-4-yl)acrylic acid 
• 1446252-31-8 (E)-ethyl 2-phenyl-3-(pyridin-4-yl)acrylate 
• 1446252-33-0 (E)-ethyl 3-(2-(tert-butoxycarbonylamino)pyridin-4-yl)-2-phenyl-acrylate 
• 1446252-36-3 (E)-ethyl 3-(2-aminopyridin-4-yl)-2-phenyl acrylate 
• 26643-91-4 4-methyl-2-phenyl-2 pentenal 
• 101-97-3 Ethyl 2-phenylethanoate 
• 54814-40-3 (E)-ethyl 3,4-dimethoxy-α-phenylcinnamate 

Relevant articles and documents

Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols

Reported herein is a general and efficient dual-deoxygenative coupling of primary alcohols with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcohols using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcohols (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence.

Reliable and versatile synthesis of 2-aryl-substituted cinnamic acid esters

2-Aryl-substituted phosphono acetates can be readily synthesized by a four-step sequence from the respective arenes. Succeeding Horner-Wadsworth- Emmons olefinations provide stereoselectively the 2-aryl cinnamic acid esters even when sensitive moieties are involved. Georg Thieme Verlag Stuttgart.

Arylation of phosphoryl-stabilized carbanions with metal π-complexes of aryl chlorides and fluorides

The nucleophilic aromatic substitution of halogen in metal arene π-complexes η6-(ArF)Cr(CO)3 and [η6-(ArHal)FeCp]+[PF6]- (Hal = F,Cl) with phosphoryl-stabilized carbanions ZCH2P(